Knowledge Management System of Hefei Institute of Physical Science,CAS
PrBaCo2-xTaxO5+delta based composite materials as cathodes for proton-conducting solid oxide fuel cells with high CO2 resistance | |
Wang, Di1; Xia, Yunpeng1; Lv, Huanlin1; Miao, Lina1; Bi, Lei2,3; Liu, Wei1,4 | |
2020-11-06 | |
发表期刊 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY |
ISSN | 0360-3199 |
通讯作者 | Bi, Lei(bilei81@gmail.com) ; Liu, Wei(wliu@ustc.edu.cn) |
摘要 | PrBaCo2O5+delta (PBC) with high catalytic activity is identified as a prospective cathode material for intermediate temperature solid oxide fuel cells (IT-SOFCs). However, its poor chemical stability hinders its application. To address this problem, a Ta-doping strategy was presented in this study. The cathode with Ta-doping PBC was applied in proton conducting SOFCs. And the influence of Ta-doping on the crystal structure, electrochemical performance, structure stability and electrical conductivity of PBC was investigated. The resistance to CO2 of PBC at elevated temperature is significantly improved with Ta-doping. The electrochemical performance measurements indicated that a low Ta-doping concentration did not change the performance of the cells obviously, while large Ta-doping concentration could lower the fuel cell performance. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
关键词 | SOFC Cathode CO2 resistance Tantalum-doping |
DOI | 10.1016/j.ijhydene.2020.08.094 |
关键词[WOS] | OXYGEN-ION DIFFUSION ; TEMPERATURE ; PEROVSKITE ; STABILITY ; MEMBRANES ; PERFORMANCE ; PERMEATION ; FE ; PRBACO2O5+DELTA ; MICROSTRUCTURE |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[U1632131] ; National Natural Science Foundation of China[21676261] ; National Natural Science Foundation of China[51972183] ; National Natural Science Foundation of China[51972297] ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion[KF2018002] ; Key Research and Development Program of Shandong Province[2019GGX103020] |
项目资助者 | National Natural Science Foundation of China ; Opening Project of CAS Key Laboratory of Materials for Energy Conversion ; Key Research and Development Program of Shandong Province |
WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
WOS类目 | Chemistry, Physical ; Electrochemistry ; Energy & Fuels |
WOS记录号 | WOS:000582322100088 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/105464 |
专题 | 中国科学院合肥物质科学研究院 |
通讯作者 | Bi, Lei; Liu, Wei |
作者单位 | 1.Univ Sci & Technol China, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, CAS Key Lab Mat Energy Convers, Hefei 230026, Peoples R China 2.Qingdao Univ, Coll Mat Sci & Engn, Inst Mat Energy & Environm, Ningxia Rd 308, Qingdao 266071, Peoples R China 3.Univ South China, Sch Resource & Environm & Safety Engn, Hengyang 421001, Peoples R China 4.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Di,Xia, Yunpeng,Lv, Huanlin,et al. PrBaCo2-xTaxO5+delta based composite materials as cathodes for proton-conducting solid oxide fuel cells with high CO2 resistance[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2020,45. |
APA | Wang, Di,Xia, Yunpeng,Lv, Huanlin,Miao, Lina,Bi, Lei,&Liu, Wei.(2020).PrBaCo2-xTaxO5+delta based composite materials as cathodes for proton-conducting solid oxide fuel cells with high CO2 resistance.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,45. |
MLA | Wang, Di,et al."PrBaCo2-xTaxO5+delta based composite materials as cathodes for proton-conducting solid oxide fuel cells with high CO2 resistance".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 45(2020). |
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