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Size-dependent surface enhanced Raman scattering activity of plasmonic AuNS@AgNCs for rapid and sensitive detection of Butyl benzyl phthalate
Wang, Qianqian1; Wang, Juan1; Li, Man2; Ge, Zipan1; Zhang, Xiang2; Luan, Longlong3; Li, Pan4; Xu, Weiping2
2021-03-05
发表期刊SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN1386-1425
通讯作者Li, Pan(lipan2011@iim.ac.cn) ; Xu, Weiping(weipingx@ustc.edu.cn)
摘要Phthalate plasticizers (PAEs) are heavily applied to plastic products and poses severe threat to human health. Herein, it is especially urgent to find a stable and reliable method for detecting PAEs. In this report, a Surface Enhanced Raman Scatting (SERS) strategy coupled with plasmonic core-shell Au nanospheres@Ag nanocubes (AuNS@AgNCs) as substrates were employed for the rapid and sensitive detection of Butyl benzyl phthalate (BBP) in liquor samples, and plasmonic core-shell AuNS@AgNCs tend to perform richer localized surface plasmon resonance (LSPR) than AuNS. In this work, different sizes AuNS@AgNCs comprised of Au nanospheres as core and Ag nanocubes as shells were synthesized. Based on this, we then investigated the SERS activity of BBP and crystal violet (CV) reached a maximum level when the thickness of Ag coating shell arrived in a threshold, and even very low signal of trace BBP dissolved in liquor sample can be detected in existence of the plasmonic AuNS@AgNCs active substrate of 50 nm. The sensitivity and repeatability of the optimized size AuNs@AgNCs have been estimated and limits of detection (LOD) was 10(-9) M for BBP. In addition, finite difference time domain (FDTD) electromagnetic simulations also performed in great agreement with our experimental results. (C) 2020 Elsevier B.V. All rights reserved.
关键词Plasticizer SERS Bimetallic substrate AuNS@AgNCs FDTD
DOI10.1016/j.saa.2020.119131
关键词[WOS]SOLID-PHASE EXTRACTION ; ACID-ESTERS ; SPECTROSCOPY ; NANOPARTICLES ; STABILITY ; BIOSENSOR ; WATER ; SERS
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[51672004] ; Natural Science Foundation of Anhui Province (China)[1608085MH176] ; Natural Science Foundation of Anhui Province (China)[1908085QB65] ; Key Research and Development Program of Anhui Province (China)[1804 h08020252]
项目资助者National Natural Science Foundation of China ; Natural Science Foundation of Anhui Province (China) ; Key Research and Development Program of Anhui Province (China)
WOS研究方向Spectroscopy
WOS类目Spectroscopy
WOS记录号WOS:000608170700007
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/119758
专题中国科学院合肥物质科学研究院
通讯作者Li, Pan; Xu, Weiping
作者单位1.Anhui Univ Chinese Med, Dept Pharm, Hefei 230038, Anhui, Peoples R China
2.Univ Sci & Technol China, Affiliated Hosp USTC 1, Div Life Sci & Med, Hefei 230001, Anhui, Peoples R China
3.Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China
4.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Hlth & Med Technol, Hefei 230021, Peoples R China
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GB/T 7714
Wang, Qianqian,Wang, Juan,Li, Man,et al. Size-dependent surface enhanced Raman scattering activity of plasmonic AuNS@AgNCs for rapid and sensitive detection of Butyl benzyl phthalate[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2021,248.
APA Wang, Qianqian.,Wang, Juan.,Li, Man.,Ge, Zipan.,Zhang, Xiang.,...&Xu, Weiping.(2021).Size-dependent surface enhanced Raman scattering activity of plasmonic AuNS@AgNCs for rapid and sensitive detection of Butyl benzyl phthalate.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,248.
MLA Wang, Qianqian,et al."Size-dependent surface enhanced Raman scattering activity of plasmonic AuNS@AgNCs for rapid and sensitive detection of Butyl benzyl phthalate".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 248(2021).
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