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The effect of annealing on spectral characteristics of the Ti doped MgAl2O4 crystal
Sun, G. H.1; Zhang, Q. L.1; Luo, J. Q.1; Li, L. C.2; Deng, Z.2; Zhang, R. G.2
2021-06-01
发表期刊JOURNAL OF LUMINESCENCE
ISSN0022-2313
通讯作者Sun, G. H.(ghsun2011@163.com)
摘要The prepared Ti:MgAl2O4 crystal samples were annealed at different temperature for 24 h in an air atmosphere, and then the transmission spectra, emission spectra, excitation spectra and photoluminescence decay curve were recorded. Furthermore, electron spin resonance of annealed samples were measured at 130 K. It is found that the absorption bands disappeared and the fluorescence intensity increased after annealed at 1200 degrees C. And when the annealing temperature is up to 1400 degrees C, the intensity of fluorescence emission was reduced significantly. These results are related to the oxidation of Ti3+ to Ti4+ and the increase of the disorder of cations. The shortening of fluorescence lifetime of the annealed samples may be related to the decrease or disappearance of oxygen vacancies.
关键词Ti:MgAl2O4 crystal Annealing Spectral characteristics
DOI10.1016/j.jlumin.2021.117956
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[51502292] ; Knowledge Innovation Program of the Chinese Academy of Sciences[CXJJ-16M251] ; Anhui Provincial Natural Science Foundation of China[1608085ME91]
项目资助者National Natural Science Foundation of China ; Knowledge Innovation Program of the Chinese Academy of Sciences ; Anhui Provincial Natural Science Foundation of China
WOS研究方向Optics
WOS类目Optics
WOS记录号WOS:000632668300002
出版者ELSEVIER
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/121284
专题中国科学院合肥物质科学研究院
通讯作者Sun, G. H.
作者单位1.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Anhui Prov Key Lab Photon Devices & Mat, Hefei 230031, Anhui, Peoples R China
2.Fujian Changting Golden Gragon Rare Earth Co Ltd, Fuzhou, Peoples R China
第一作者单位中科院安徽光学精密机械研究所
通讯作者单位中科院安徽光学精密机械研究所
推荐引用方式
GB/T 7714
Sun, G. H.,Zhang, Q. L.,Luo, J. Q.,et al. The effect of annealing on spectral characteristics of the Ti doped MgAl2O4 crystal[J]. JOURNAL OF LUMINESCENCE,2021,234.
APA Sun, G. H.,Zhang, Q. L.,Luo, J. Q.,Li, L. C.,Deng, Z.,&Zhang, R. G..(2021).The effect of annealing on spectral characteristics of the Ti doped MgAl2O4 crystal.JOURNAL OF LUMINESCENCE,234.
MLA Sun, G. H.,et al."The effect of annealing on spectral characteristics of the Ti doped MgAl2O4 crystal".JOURNAL OF LUMINESCENCE 234(2021).
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