Enhanced Fenton-like degradation of sulfadiazine by single atom iron materials fixed on nitrogen-doped porous carbon

doi:10.1016/j.jcis.2021.03.168

HFCAS OpenIR

	Enhanced Fenton-like degradation of sulfadiazine by single atom iron materials fixed on nitrogen-doped porous carbon
	Yang, Wu 1,2,3; Hong, Peidong 3,4; Yang, Dandan 3,4; Yang, Ya 3,4; Wu, Zijian 3; Xie, Chao 3; He, Junyong 3; Zhang, Kaisheng 3; Kong, Lingtao3 ; Liu, Jinhuai1,2,3
	2021-09-01
发表期刊	JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN	0021-9797
通讯作者	Zhang, Kaisheng(kszhang@iim.ac.cn) ; Kong, Lingtao(ltkong@iim.ac.cn) ; Liu, Jinhuai(jhliu@iim.ac.cn)
摘要	The use of single-atom iron catalysts in heterogeneous Fenton-like reactions has demonstrated tremendous potential for antibiotic wastewater treatment. In this study, single-atom iron fixed on nitrogen-doped porous carbon materials (Fe-ISAs@CN) was synthesised using a metal organic framework (MOF) as a precursor. Fe-ISAs@CN was applied as a heterogeneous Fenton catalyst to activate H2O2 for the degradation of sulfadiazine (SDZ) in an aqueous solution. The physical and chemical properties of Fe-ISAs@CN were characterised by scanning electron microscopy (SEM), transmission electron microscope (TEM), high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and rotating disk electrode (RDE) measurements. The results of our degradation experiments indicated that Fe-ISAs@CN exhibited remarkable activity and stability for the degradation of SDZ over a wide pH range; even after five cycles, Fe-ISAs@CN retained a high catalytic efficiency (>80%). The 5,5-dimethyl-1-oxaporphyrin-n-oxide (DMPO)-X signal captured by electron paramagnetic resonance (EPR) spectroscopy indicated that a large amount of hydroxyl radicals ((OH)-O-center dot) was produced in the reaction system. Quench tests indicated that the (OH)-O-center dot was the main active substance in the degradation of SDZ. The degradation products of the reaction were analysed by High Performance Liquid Chromatography-Mass Spectrometry (HPLC-MS), and possible degradation pathways for the SDZ degradation were proposed. (C) 2021 Elsevier Inc. All rights reserved.
关键词	Single-atom iron Sulfadiazine Fenton-like reaction Highly efficient catalyst Catalysis mechanism
DOI	10.1016/j.jcis.2021.03.168
关键词[WOS]	ANTIBIOTIC-RESISTANCE ; WATER ; OXIDATION ; PEROXYMONOSULFATE ; BIODEGRADABILITY ; SULFAMETHOXAZOLE ; DECOMPOSITION ; MECHANISM ; CATALYSTS ; RESIDUES
收录类别	SCI
语种	英语
资助项目	State Key Research Development Program of China[2019YFC0408505] ; Natural Science Foundation of China[21976182] ; National Key Research Development Program of China Technology Boosts Economy 2020 ; Natural Science Foundation of Anhui Province[2008085MB48] ; Program of China-Sri Lanka Joint Research and Demonstration Centre for Water Technology ; China-Sri Lanka Joint Center for Education and Research by Chinese Academy of Sciences, China
项目资助者	State Key Research Development Program of China ; Natural Science Foundation of China ; National Key Research Development Program of China Technology Boosts Economy 2020 ; Natural Science Foundation of Anhui Province ; Program of China-Sri Lanka Joint Research and Demonstration Centre for Water Technology ; China-Sri Lanka Joint Center for Education and Research by Chinese Academy of Sciences, China
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:000653054800007
出版者	ACADEMIC PRESS INC ELSEVIER SCIENCE
引用统计	被引频次：53[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/122090
专题	中国科学院合肥物质科学研究院
通讯作者	Zhang, Kaisheng; Kong, Lingtao; Liu, Jinhuai
作者单位	1.Anhui Univ, Inst Phys Sci, Hefei 230601, Peoples R China 2.Anhui Univ, Inst Informat Technol, Hefei 230601, Peoples R China 3.Chinese Acad Sci, Inst Solid State Phys, Environm Mat & Pollut Control Lab, HFIPS, Hefei 230031, Peoples R China 4.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Yang, Wu,Hong, Peidong,Yang, Dandan,et al. Enhanced Fenton-like degradation of sulfadiazine by single atom iron materials fixed on nitrogen-doped porous carbon[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2021,597.
APA	Yang, Wu.,Hong, Peidong.,Yang, Dandan.,Yang, Ya.,Wu, Zijian.,...&Liu, Jinhuai.(2021).Enhanced Fenton-like degradation of sulfadiazine by single atom iron materials fixed on nitrogen-doped porous carbon.JOURNAL OF COLLOID AND INTERFACE SCIENCE,597.
MLA	Yang, Wu,et al."Enhanced Fenton-like degradation of sulfadiazine by single atom iron materials fixed on nitrogen-doped porous carbon".JOURNAL OF COLLOID AND INTERFACE SCIENCE 597(2021).