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In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions
Zhang, Jifang1,2; Gong, Wanbing1; Yin, Huajie1,3; Wang, Dongdong1,2; Zhang, Yunxia1; Zhang, Haimin1; Wang, Guozhong1; Zhao, Huijun1,3
2021-06-09
Source PublicationCHEMSUSCHEM
ISSN1864-5631
Corresponding AuthorGong, Wanbing(wbgong@issp.ac.cn) ; Zhao, Huijun(h.zhao@griffith.edu.au)
AbstractDevelopment of electrocatalysts that are capable of efficiently oxidizing biomass-derived 5-hydroxymethylfurfural (HMF) into 2,5-furandicarboxylic acid (FDCA) is critically important for production of degradable plastics via non-fossil routes. In this study, a facile and scalable immersion synthetic approach has been developed to grow ultrathin nickel hydroxide nanosheets in situ on commercial nickel foam (Ni(OH)(2)/NF) as an anode for the electrocatalytic oxidation of HMF to FDCA with complete HMF conversion, 100 % FDCA yield, and >99 % faradaic efficiency at 1.39 V (vs. RHE) within 90 min. Mechanistic studies reveal that the initial oxidation of HMF takes place at the carbonyl group and FDCA is generated through two further oxidation steps. Impressively, the synthesized Ni(OH)(2)/NF can also be used to electrocatalytically oxidize other alcohol/aldehyde-containing compounds to the targeted products in alkaline medium with 100 % yield and >94 % faradaic efficiency under a low oxidation potential of 1.39 V (vs. RHE) within short reaction times.
Keywordbiomass valorization electrocatalysis 5-hydroxymethylfurfural nickel oxidation
DOI10.1002/cssc.202100811
WOS KeywordELECTROCHEMICAL OXIDATION ; OXYGEN EVOLUTION ; 2,5-FURANDICARBOXYLIC ACID ; HYDROGEN-PRODUCTION ; EFFICIENT ; WATER
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[51902311]
Funding OrganizationNational Natural Science Foundation of China
WOS Research AreaChemistry ; Science & Technology - Other Topics
WOS SubjectChemistry, Multidisciplinary ; Green & Sustainable Science & Technology
WOS IDWOS:000659413500001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/123723
Collection中国科学院合肥物质科学研究院
Corresponding AuthorGong, Wanbing; Zhao, Huijun
Affiliation1.Chinese Acad Sci, CAS Ctr Excellence Nanosci,Inst Solid State Phys, Ctr Environm & Energy Nanomat,HFIPS, Anhui Key Lab Nanomat & Nanotechnol,Key Lab Mat P, Hefei 230031, Peoples R China
2.Univ Sci & Technol China, Hefei 230026, Peoples R China
3.Griffith Univ, Ctr Clean Environm & Energy, Gold Coast Campus, Gold Coast, Qld 4222, Australia
Recommended Citation
GB/T 7714
Zhang, Jifang,Gong, Wanbing,Yin, Huajie,et al. In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions[J]. CHEMSUSCHEM,2021.
APA Zhang, Jifang.,Gong, Wanbing.,Yin, Huajie.,Wang, Dongdong.,Zhang, Yunxia.,...&Zhao, Huijun.(2021).In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions.CHEMSUSCHEM.
MLA Zhang, Jifang,et al."In Situ Growth of Ultrathin Ni(OH)(2) Nanosheets as Catalyst for Electrocatalytic Oxidation Reactions".CHEMSUSCHEM (2021).
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