IR Spectral Inversion of Methane Concentration and Emission Rate in Shale Gas Backflow

doi:10.3964/j.issn.1000-0593(2021)12-3717-05

HFCAS OpenIR

	IR Spectral Inversion of Methane Concentration and Emission Rate in Shale Gas Backflow
	Cheng Xiao-xiao 1,2; Liu Jian-guo1 ; Xu Liang1 ; Xu Han-yang1 ; Jin Ling1 ; Xue Ming 3
	2021-12-01
发表期刊	SPECTROSCOPY AND SPECTRAL ANALYSIS
ISSN	1000-0593
通讯作者	Xu Liang(xuliang@aiofm.ac.cn)
摘要	With the development of shale gas, the traditional handheld methane meter cannot cope with the complex shale gas production conditions due to the need for manual contact sampling. In view of the difficulty of real-time online monitoring of the emission concentration and rate of greenhouse gas methane in the process of shale gas development, we use the self-designed and built open Fourier transform infrared ( FTIR) measurement system to measure the backflow liquid under various working conditions in the process of shale gas production. The FTIR resolution is 1 cm(-1) and the optical path is 50 m. The light source passes directly above the backflow liquid and is received by the spectrometer. The measured infrared spectra are averaged several times, the hyperspectral mass is maintained, and the inverse calculation is carried out. The absorption cross-section calculated from the HITRAN database, considering the influence of environment and instruments, the measured temperature was modified, the appropriate methane absorption band was selected, and the absorption peak was superimposed with the absorption cross-section of water vapor to synthesize the standard spectrum. The methane concentration was calculated by fitting the measured spectrum with the standard spectrum using the least square method. The methane emission rate during shale gas exploitation was calculated according to the emission rate of the backflow fluid and combining the distance of the light path through the backflow pool and the infrared spectrum inversion concentration. The results show that spectral inversion concentration fluctuates obviously under different mining conditions. When the three separators were replaced, the methane concentration increased obviously. When the torch was lit, the methane concentration continued to be low, and the results of infrared spectrum inversion concentration were consistent with the methane emission in shale gas development and construction. The spectrum was averaged several times to improve the spectral quality, and methane in the backflow liquid was measured in a unit hour and continuous 80 hours. Within the unit hour, the methane concentration fluctuated within the range of 100 similar to 800 mu mol . mol(-1) , and the variation trend was continuous and obvious. The emission rate of methane fluctuated between 50 and 300 m(3) . h(-1). After 80 hour' continuous measurement of the backflow fluid, the maximum methane concentration was 936. 4 mu mol. mol(-1) , and the maximum emission rate reached 535. 1 m(3) . h(-1) . The lowest value was 36. 82 mu mol . mol(-1) , and its minimum emission rate was 18. 63 m(3) . h(-1) . The result of inversion data shows that the backflow fluid is an irregular methane emission source in the development process of shale gas, and the change is very obvious in a short time. At the same time, the infrared spectrum inversion concentration was compared with the results of the traditional handheld methane measurement instrument, and the correlation coefficient was 0.743 6. Compared with the traditional handheld methane measurement instrument, the infrared spectral inversion method has the advantages of faster response, non-contact distance, real-time online measurement, etc.
关键词	Shale gas CH4 Spectral inversion Concentration Emission rate
DOI	10.3964/j.issn.1000-0593(2021)12-3717-05
收录类别	SCI
语种	英语
WOS研究方向	Spectroscopy
WOS类目	Spectroscopy
WOS记录号	WOS:000747245000012
出版者	OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS
引用统计
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/127588
专题	中国科学院合肥物质科学研究院
通讯作者	Xu Liang
作者单位	1.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei Inst Phys Sci, Key Lab Environm Opt & Technol, Hefei 230031, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Peoples R China 3.CNPC Res Inst Safety & Environm Technol, State Key Lab Petr Pollut Control, Beijing 102206, Peoples R China
第一作者单位	中科院安徽光学精密机械研究所
通讯作者单位	中科院安徽光学精密机械研究所
推荐引用方式 GB/T 7714	Cheng Xiao-xiao,Liu Jian-guo,Xu Liang,et al. IR Spectral Inversion of Methane Concentration and Emission Rate in Shale Gas Backflow[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2021,41.
APA	Cheng Xiao-xiao,Liu Jian-guo,Xu Liang,Xu Han-yang,Jin Ling,&Xue Ming.(2021).IR Spectral Inversion of Methane Concentration and Emission Rate in Shale Gas Backflow.SPECTROSCOPY AND SPECTRAL ANALYSIS,41.
MLA	Cheng Xiao-xiao,et al."IR Spectral Inversion of Methane Concentration and Emission Rate in Shale Gas Backflow".SPECTROSCOPY AND SPECTRAL ANALYSIS 41(2021).