Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen

doi:10.1002/anie.202208751

HFCAS OpenIR

	Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen
	Zhuang, Shengli 1,2,3; Chen, Dong 4; You, Qing 1,2,3; Fan, Wentao 1,2,3,5; Yang, Jun 4; Wu, Zhikun1,2,3
	2022-10-18
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
通讯作者	Yang, Jun(jyang@ipe.ac.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
摘要	Although thiolated, reduced Group 11 metal nanoclusters with atomic monodispersity have been repeatedly reported in the past decade, their Pd analogues have not been reported thus far. In this work, we provide a resolution for the challenging synthesis and obtain for the first time an atomically monodisperse thiolated, reduced Pd (q=+0.75) nanocluster with a di-tetrahedron Pd-8 kernel and a +3 charged interstitial B atom, as revealed by ESI-MS, SCXRD, etc. mu-6 B is found for the first time in Group 10 and 11 metal nanoclusters. More importantly, the as-obtained Pd nanoclusters show better catalytic activity compared to 1.4 nm Pd nanoparticles, Pd-2 complexes and even a commercial Pt/C catalyst for the oxygen reduction reaction (ORR), having significant implications for the influence of the metal charge state and space structure on the catalytic activity.
关键词	Electrocatalysis Interstitial B Atom ORR Nanoclusters Palladium
DOI	10.1002/anie.202208751
关键词[WOS]	PROTECTED GOLD ; METAL BORIDE ; NANOPARTICLES ; SILVER ; CATALYSIS ; CLUSTERS
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21905284] ; National Natural Science Foundation of China[21829501] ; National Natural Science Foundation of China[21925303] ; National Natural Science Foundation of China[22075290] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21528303] ; China Postdoctoral Science Foundation[Y94G4E356B] ; Key Program of 13th five-year plan[KP-2017-16] ; Collaborative Innovation Program of Hefei Science Center, CAS[2020HSC-CIP005] ; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences, State Key Laboratory of Multiphase Complex Systems[MPCS-2021-A-05]
项目资助者	National Natural Science Foundation of China ; China Postdoctoral Science Foundation ; Key Program of 13th five-year plan ; Collaborative Innovation Program of Hefei Science Center, CAS ; Center for Mesoscience, Institute of Process Engineering, Chinese Academy of Sciences, State Key Laboratory of Multiphase Complex Systems
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000869649500001
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：20[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/129465
专题	中国科学院合肥物质科学研究院
通讯作者	Yang, Jun; Wu, Zhikun
作者单位	1.Chinese Acad Sci, CAS Ctr Excellence Nanosci, Inst Solid State Phys, Key Lab Mat Phys,Anhui Key Lab Nanomat & Nanotech, Hefei 230031, Peoples R China 2.Anhui Univ, Dept Chem, Hefei 230601, Anhui, Peoples R China 3.Anhui Univ, Ctr Atom Engn Adv Mat, Hefei 230601, Anhui, Peoples R China 4.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 5.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
推荐引用方式 GB/T 7714	Zhuang, Shengli,Chen, Dong,You, Qing,et al. Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2022.
APA	Zhuang, Shengli,Chen, Dong,You, Qing,Fan, Wentao,Yang, Jun,&Wu, Zhikun.(2022).Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Zhuang, Shengli,et al."Thiolated, Reduced Palladium Nanoclusters with Resolved Structures for the Electrocatalytic Reduction of Oxygen".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022).