Buffer electrode layers tuned electrical properties, fatigue behavior and phase transition of KNN-based lead-free ferroelectric films

doi:10.1039/d3tc02743k

HFCAS OpenIR

	Buffer electrode layers tuned electrical properties, fatigue behavior and phase transition of KNN-based lead-free ferroelectric films
	Xu, Liqiang 1,2; Zhu, Beibei 1,2; Dai, Song 1,2; Han, Kun 1,2; Chen, Pingfan 1,2; Wang, Ke5 ; Huang, Zhen 1,2,6; Wu, Wenbin3,4 ; Chen, Feng3
	2023-10-19
发表期刊	JOURNAL OF MATERIALS CHEMISTRY C
ISSN	2050-7526
通讯作者	Huang, Zhen(huangz@ahu.edu.cn) ; Chen, Feng(fchen@hmfl.ac.cn)
摘要	This study investigates the impact of different conductive buffer electrode layers on the electrical properties, fatigue behavior and phase transition of epitaxial KNN-based ferroelectric films. Two types of buffer electrode layers, p-type La0.67Ca0.33MnO3/La0.67Ba0.33MnO3 and n-type LaNiO3/Nb-SrTiO3, are selected for analysis. The results demonstrate that the electrical properties and fatigue behavior of the KNN-based films are significantly influenced by the buffer electrode layers. Specifically, the KNN-based films buffered with p-type electrodes exhibit superior ferroelectric/dielectric properties and fatigue resistance compared to those buffered with n-type electrodes. The ferroelectric hysteresis loops of p-type electrode buffered KNN-based films demonstrate higher saturation, larger twice remnant polarization (2Pr) and higher dielectric constant (epsilon) (2Pr = 58.5/46.9 mu C cm-2 and epsilon = 1290/1003 for La0.67Ca0.33MnO3/La0.67Ba0.33MnO3-buffered KNNLT-M films) compared to the films grown on n-type electrodes (2Pr = 29.5/24.5 mu C cm-2 and epsilon = 802/668 for LaNiO3/Nb-SrTiO3-buffered KNNLT-M films). Moreover, the KNN-based films grown on p-type buffer electrode layers exhibit high fatigue resistance, maintaining consistent ferroelectric hysteresis loops even after 108 bipolar switching cycles, while those on n-type buffer electrode layers experience dramatic fatigue after only 106 cycles. Temperature-dependent dielectric analysis reveals that all studied KNN-based films exhibit relaxor ferroelectric behavior, with the p-type electrode buffered films exhibiting higher phase transition temperatures than the n-type electrode buffered films. These findings demonstrate that the conductive type of the buffer electrode layer can effectively tune the performance of KNN-based films, indicating the high application potential in lead-free electronic device. Herein, the impact of conductive buffer electrode layers (p- or n-type) on the electrical properties and fatigue behavior of KNN-based ferroelectric films are investigated.
DOI	10.1039/d3tc02743k
关键词[WOS]	PIEZOCERAMICS
收录类别	SCI
语种	英语
资助项目	This work was supported by the National Natural Science Foundation of China (Grant No. 12374095, 12204005, 12074001, 12104008, 12104002, 11974326, 52032005, and U2032218), Anhui Provincial Higher-Education Natural Science Research Project (Grant No. K12046
项目资助者	This work was supported by the National Natural Science Foundation of China (Grant No. 12374095, 12204005, 12074001, 12104008, 12104002, 11974326, 52032005, and U2032218), Anhui Provincial Higher-Education Natural Science Research Project (Grant No. K12046
WOS研究方向	Materials Science ; Physics
WOS类目	Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号	WOS:001082601100001
出版者	ROYAL SOC CHEMISTRY
引用统计
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/133392
专题	中国科学院合肥物质科学研究院
通讯作者	Huang, Zhen; Chen, Feng
作者单位	1.Anhui Univ, Inst Phys Sci, Informat Mat & Intelligent Sensing Lab Anhui Prov, Hefei 230601, Peoples R China 2.Anhui Univ, Inst Informat Technol, Informat Mat & Intelligent Sensing Lab Anhui Prov, Hefei 230601, Peoples R China 3.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme, High Magnet Field Lab, Hefei 230031, Anhui, Peoples R China 4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China 5.Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China 6.Anhui Univ, Stony Brook Inst Anhui Univ, Hefei 230039, Peoples R China
推荐引用方式 GB/T 7714	Xu, Liqiang,Zhu, Beibei,Dai, Song,et al. Buffer electrode layers tuned electrical properties, fatigue behavior and phase transition of KNN-based lead-free ferroelectric films[J]. JOURNAL OF MATERIALS CHEMISTRY C,2023,11.
APA	Xu, Liqiang.,Zhu, Beibei.,Dai, Song.,Han, Kun.,Chen, Pingfan.,...&Chen, Feng.(2023).Buffer electrode layers tuned electrical properties, fatigue behavior and phase transition of KNN-based lead-free ferroelectric films.JOURNAL OF MATERIALS CHEMISTRY C,11.
MLA	Xu, Liqiang,et al."Buffer electrode layers tuned electrical properties, fatigue behavior and phase transition of KNN-based lead-free ferroelectric films".JOURNAL OF MATERIALS CHEMISTRY C 11(2023).