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Photo-excited in situ loading of Pt clusters onto rGO immobilized SnO2 with excellent catalytic performance toward methanol oxidation
Wu, Shouliang1,2; Liu, Jun1,2; Liang, Dewei1,2,3; Sun, Hongmei1,2,3; Ye, Yixing1,2; Tian, Zhenfei1,2; Liang, Changhao1,2,3
2016-08-01
Source PublicationNANO ENERGY
AbstractMaximizing the surface area and the exposed active sites of Pt-based catalysts is one of the most effective strategies to improve their electrocatalytic performance. We here present an environmentally friendly construction of a two-dimensional Pt/SnO2/reduced-graphene-oxide (rGO) nanocomposite as a active and durable electrocatalyst. Initially, liquid-phase laser ablation generated highly reactive SnO nano particles (NPs) were used as a precursor to transform the graphene oxide into rGO. Simultaneously, the initial amorphous-like SnO can further crystallize into SnO2 NPs, which were uniformly anchored onto rGO sheets. Subsequently, the electrons photo-excited from semiconductor SnO2 were used as green reducing agents, which can in situ reduce the PtCl62- ions to form ultrafine Pt NPs with an average size of about 1-2 nm that uniformly dispersed onto SnO2 NPs. Compared with Pt/rGO catalysts without SnO2 modification, the Pt/SnO2/rGO hybrid ternary catalysts not only show larger electrochemical active surface area and higher catalytic activity toward methanol oxidation, but also exhibit better long-term cycle stability and better tolerance toward CO-like species. Such significantly enhanced electrochemical performance could be attributed to the uniformly dispersed fine Pt NPs and the synergetic effect from the hybrid noble metal-semiconductor-carbon network components. (C) 2016 Elsevier Ltd. All rights reserved.
SubtypeArticle
KeywordPt Cluster Hybrid Composite Electrocatalyst Photo-excited Reduction Methanol Oxidation Laser Ablation In Liquids
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.nanoen.2016.06.038
WOS KeywordREDUCED GRAPHENE OXIDE ; HIGH ELECTROCATALYTIC ACTIVITY ; FUEL-CELLS ; NANOTUBE ARRAYS ; ANODE CATALYST ; NANOPARTICLES ; NANOSHEETS ; HYBRID ; NANOCOMPOSITES ; DEGRADATION
Indexed BySCI
Language英语
Funding OrganizationNational Basic Research Program of China(2014CB931704) ; National Basic Research Program of China(2014CB931704) ; National Basic Research Program of China(2014CB931704) ; National Basic Research Program of China(2014CB931704) ; National Basic Research Program of China(2014CB931704) ; National Basic Research Program of China(2014CB931704) ; National Basic Research Program of China(2014CB931704) ; National Basic Research Program of China(2014CB931704) ; National Natural Science Foundation of China (NSFC)(51371166 ; National Natural Science Foundation of China (NSFC)(51371166 ; National Natural Science Foundation of China (NSFC)(51371166 ; National Natural Science Foundation of China (NSFC)(51371166 ; National Natural Science Foundation of China (NSFC)(51371166 ; National Natural Science Foundation of China (NSFC)(51371166 ; National Natural Science Foundation of China (NSFC)(51371166 ; National Natural Science Foundation of China (NSFC)(51371166 ; 11504375 ; 11504375 ; 11504375 ; 11504375 ; 11504375 ; 11504375 ; 11504375 ; 11504375 ; 11304315) ; 11304315) ; 11304315) ; 11304315) ; 11304315) ; 11304315) ; 11304315) ; 11304315)
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000384908700080
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/21167
Collection中科院固体物理研究所
Affiliation1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Peoples R China
2.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Hefei 230031, Peoples R China
3.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
Recommended Citation
GB/T 7714
Wu, Shouliang,Liu, Jun,Liang, Dewei,et al. Photo-excited in situ loading of Pt clusters onto rGO immobilized SnO2 with excellent catalytic performance toward methanol oxidation[J]. NANO ENERGY,2016,26(无):699-707.
APA Wu, Shouliang.,Liu, Jun.,Liang, Dewei.,Sun, Hongmei.,Ye, Yixing.,...&Liang, Changhao.(2016).Photo-excited in situ loading of Pt clusters onto rGO immobilized SnO2 with excellent catalytic performance toward methanol oxidation.NANO ENERGY,26(无),699-707.
MLA Wu, Shouliang,et al."Photo-excited in situ loading of Pt clusters onto rGO immobilized SnO2 with excellent catalytic performance toward methanol oxidation".NANO ENERGY 26.无(2016):699-707.
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