High-temperature Raman spectroscopic study of vanadoborate Na3VO2B6O11

doi:10.1088/1674-1056/25/3/037802

	High-temperature Raman spectroscopic study of vanadoborate Na3VO2B6O11
	Zhang, Ji 1; Zhang, De-Ming2 ; Zhang, Qing-Li2 ; Yin, Shao-Tang 2
	2016-03-01
发表期刊	CHINESE PHYSICS B
摘要	Raman spectra of a vanadoborate (Na3VO2B6O11) crystal from room temperature up to the melting point have been recorded. The main internal vibrational modes of the crystal have been assigned. It was found that all the Raman bands exhibit decreases in frequency and the widths of the Raman bands increase with the increase of temperature. However, no phase transition was observed under 525 degrees C. The micro-structure of its melt was studied by quantum chemistry ab initio calculation. The continuous three-dimensional network of the crystal collapsed and transformed into VO4 and VBO6 clusters during the melting process with an isomerization reaction from four-coordinated boron to a three-coordinated species.
文章类型	Article
关键词	Na3vo2b6o11 Crystal High-temperature Raman Spectroscopy Vibration Mode
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1088/1674-1056/25/3/037802
关键词[WOS]	NONLINEAR-OPTICAL CRYSTAL ; INFRARED REFLECTANCE ; SPECTRA ; MICROSTRUCTURE ; LIB3O5 ; GROWTH
收录类别	SCI
语种	英语
项目资助者	National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; National Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; Natural Science Foundation of Anhui Province, China(KJ2015A339) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239) ; 51102239)
WOS研究方向	Physics
WOS类目	Physics, Multidisciplinary
WOS记录号	WOS:000375647400063
引用统计	被引频次：2[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/21310
专题	中科院安徽光学精密机械研究所
作者单位	1.An Hui Xin Hua Univ, Hefei 230088, Peoples R China 2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Ji,Zhang, De-Ming,Zhang, Qing-Li,et al. High-temperature Raman spectroscopic study of vanadoborate Na3VO2B6O11[J]. CHINESE PHYSICS B,2016,25(3):037802.
APA	Zhang, Ji,Zhang, De-Ming,Zhang, Qing-Li,&Yin, Shao-Tang.(2016).High-temperature Raman spectroscopic study of vanadoborate Na3VO2B6O11.CHINESE PHYSICS B,25(3),037802.
MLA	Zhang, Ji,et al."High-temperature Raman spectroscopic study of vanadoborate Na3VO2B6O11".CHINESE PHYSICS B 25.3(2016):037802.

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