Institutional Repository of Chinese Academy of Sciences, Institute of Plasma Physics, Hefei 230031, Anhui, Peoples R China
Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines | |
Wu, Jun1,2; Liu, Chun-Xiang1,2; Wang, Hui-Juan3; Li, Fa-Bao1,2; Shi, Ji-Long1,2; Liu, Li1,2; Li, Jia-Xing4; Liu, Chao-Yang3; Huang, Yong-Shun4 | |
2016-10-07 | |
发表期刊 | JOURNAL OF ORGANIC CHEMISTRY |
摘要 | The facile one-step reaction of [60]fullerene with aldehydes and primary amines in the presence of cheap and easily available Cu(OAc)(2)center dot H2O afforded a series of new types of fulleropyrrolines with trisubstituted C=C bonds in good to excellent yields, which would be difficult to prepare by known methods. The formed fulleropyrroline under the assistance of Pd(OAc)(2) and CuCl2 center dot 2H(2)O could be further converted to 1-fulleropyrrolidine by the chlorohydroxylation reaction of C=C bond. Subsequent elimination reaction of 1-fulleropyrrolidine with the aid of TsOH center dot H2O generated the scarce 1-fulleropyrroline derivative. |
文章类型 | Article |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1021/acs.joc.6b01875 |
关键词[WOS] | ONE-STEP REACTION ; ASYMMETRIC CHLOROHYDRIN SYNTHESIS ; MANGANESE(III) ACETATE DIHYDRATE ; MEDIATED RADICAL REACTIONS ; FERRIC PERCHLORATE ; FACILE ACCESS ; 60 FULLERENE ; DERIVATIVES ; STEREOCHEMISTRY ; CHEMISTRY |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; National Natural Science Foundation of China(21102041 ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Foundation of Hubei Province(2014CFB550) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Natural Science Fund for Creative Research Groups of Hubei Province of China(2014CFA015) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; Innovation and Entrepreneurship Training Program for Undergraduates of Hubei Province(201610512054) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) ; 21272236) |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
WOS记录号 | WOS:000385054300059 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/21410 |
专题 | 中科院等离子体物理研究所 |
作者单位 | 1.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Peoples R China 2.Hubei Univ, Sch Chem & Chem Engn, Wuhan 430062, Peoples R China 3.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China 4.Chinese Acad Sci, Inst Plasma Phys, Key Lab Novel Thin Film Solar Cells, POB 1126, Hefei 230031, Peoples R China |
推荐引用方式 GB/T 7714 | Wu, Jun,Liu, Chun-Xiang,Wang, Hui-Juan,et al. Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines[J]. JOURNAL OF ORGANIC CHEMISTRY,2016,81(19):9296-9307. |
APA | Wu, Jun.,Liu, Chun-Xiang.,Wang, Hui-Juan.,Li, Fa-Bao.,Shi, Ji-Long.,...&Huang, Yong-Shun.(2016).Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines.JOURNAL OF ORGANIC CHEMISTRY,81(19),9296-9307. |
MLA | Wu, Jun,et al."Cu(OAc)(2)-Mediated Reaction of [60]Fullerene with Aldehydes and Primary Amines for the Synthesis of Fulleropyrrolines".JOURNAL OF ORGANIC CHEMISTRY 81.19(2016):9296-9307. |
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