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Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering
Zhang, Duan1; Wu, Ye-Cun1; Yang, Mei1; Liu, Xiao1; Coileain, Cormac O.1,2,3; Xu, Hongjun1,2; Abid, Mourad2; Abid, Mohamed2; Wang, Jing-Jing3; Shvets, Igor V.3; Liu, Haonan1; Wang, Zhi1; Yin, Hongxing1; Liu, Huajun4; Chun, Byong Sun5; Zhang, Xiangdong1; Wu, Han-Chun1
2016
发表期刊RSC ADVANCES
摘要Monolayer transition metal dichalcogenides exhibit remarkable electronic and optical properties, making them candidates for application within flexible nano-optoelectronics, however direct experimental determination of their thermal expansion coefficients (TECs) is difficult. Here, we propose a non-destructive method to probe the TECs of monolayer materials using surface-enhanced Raman spectroscopy (SERS). A strongly coupled Ag nanoparticle over-layer is used to controllably introduce temperature dependent strain in monolayers. Changes in the first-order temperature coefficient of the Raman shift, produced by TEC mismatch, can be used to estimate relative expansion coefficient of the monolayer. As a demonstration, the linear TEC of monolayer WS2 is probed and is found to be 10.3 x 10(-6) K-1, which would appear support theoretical predictions of a small TEC. This method opens a route to probe and control the TECs of monolayer materials.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
DOI10.1039/c6ra20623a
关键词[WOS]TRANSITION-METAL DICHALCOGENIDES ; TEMPERATURE-DEPENDENT RAMAN ; MOS2 TRANSISTORS ; LAYER MOS2 ; GRAPHENE ; WS2 ; PHONON ; WSE2 ; OPTOELECTRONICS ; CRYSTALS
收录类别SCI
语种英语
项目资助者Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; Beijing Institute of Technology Research Fund Program for Young Scholars of King Abdulaziz City for Science and Technology ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; National Plan for Science and technology of King Abdulaziz City for Science and Technology(NPST 2472-02 ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; Saudi Aramco(6600028398) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02) ; NPST 2529-02)
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000387427800060
引用统计
被引频次：20[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/21893
专题中科院等离子体物理研究所
作者单位1.Beijing Inst Technol, Sch Phys, Beijing Key Lab Nanophoton & Ultrafine Optoelect, Beijing 100081, Peoples R China
2.King Saud Univ, KSU Aramco Ctr, Riyadh 11451, Saudi Arabia
3.Univ Dublin, Trinity Coll, Sch Phys, CRANN, Dublin 2, Ireland
4.Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Peoples R China
5.Korea Res Inst Stand & Sci, Div Ind Metrol, Daejeon 305340, South Korea
推荐引用方式
GB/T 7714		 Zhang, Duan,Wu, Ye-Cun,Yang, Mei,et al. Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering[J]. RSC ADVANCES,2016,6(101):99053-99059.
APA Zhang, Duan.,Wu, Ye-Cun.,Yang, Mei.,Liu, Xiao.,Coileain, Cormac O..,...&Wu, Han-Chun.(2016).Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering.RSC ADVANCES,6(101),99053-99059.
MLA Zhang, Duan,et al."Probing thermal expansion coefficients of monolayers using surface enhanced Raman scattering".RSC ADVANCES 6.101(2016):99053-99059.
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