Institutional Repository of Chinese Acad Sci, High Field Magnet Lab,Hefei 230031, Anhui, Peoples R China
| Pd-Co-3[Co(CN)(6)](2) hybrid nanoparticles: preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions | |
Li, Ren1,3; Li, Ran1; Wang, Changlai1; Gao, Lei2; Chen, Qianwang1,2
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| 2016 | |
| 发表期刊 | DALTON TRANSACTIONS
 |
| 摘要 | Because of their abundance and low cost, organo chlorides are the most desirable substrates from the industrial point of view in Suzuki-Miyaura cross-coupling reactions. However, catalytic application of Pd nanoparticles (NPs) for Suzuki coupling of aryl chlorides is still a challenge. Here, we design a novel catalyst by combining Pd NPs with Co-3[Co(CN)(6)](2) nanocrystals for Suzuki-Miyaura coupling of aryl chlorides. This nanocatalyst demonstrated good activity (yield 86.2% at 80 degrees C), high TOF, great stability, easy separation, excellent reusability (initial rates were not reduced after five cycles) and low cost in Suzuki reactions. |
| 文章类型 | Article |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c5dt03631c |
| 关键词[WOS] | METAL-ORGANIC FRAMEWORKS ; PRUSSIAN BLUE ANALOG ; HETEROGENEOUS CATALYSIS ; PALLADIUM COMPLEXES ; HYDROGEN STORAGE ; POLYMERS ; METHANE ; DESIGN ; WATER |
| 收录类别 | SCI |
| 语种 | 英语 |
| 项目资助者 | National Natural Science Foundation(21271163 ; National Natural Science Foundation(21271163 ; National Natural Science Foundation(21271163 ; National Natural Science Foundation(21271163 ; CAS/SAFEA international partnership program ; CAS/SAFEA international partnership program ; CAS/SAFEA international partnership program ; CAS/SAFEA international partnership program ; china scholarship council (CSC)(201500730008) ; china scholarship council (CSC)(201500730008) ; china scholarship council (CSC)(201500730008) ; china scholarship council (CSC)(201500730008) ; U1232211) ; U1232211) ; U1232211) ; U1232211) |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear |
| WOS记录号 | WOS:000367312900020 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/22218 |
| 专题 | 中科院强磁场科学中心 |
| 作者单位 | 1.Univ Sci & Technol China, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Dept Mat Sci & Engn, Hefei Natl Lab Phys Sci Microscales, Hefei 230026, Peoples R China 2.Chinese Acad Sci, High Magnet Field Lab, Hefei, Peoples R China 3.Univ Namur, Lab Inorgan Mat Chem CMI, B-5000 Namur, Belgium |
| 推荐引用方式 GB/T 7714 | Li, Ren,Li, Ran,Wang, Changlai,et al. Pd-Co-3[Co(CN)(6)](2) hybrid nanoparticles: preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions[J]. DALTON TRANSACTIONS,2016,45(2):539-544. |
| APA | Li, Ren,Li, Ran,Wang, Changlai,Gao, Lei,&Chen, Qianwang.(2016).Pd-Co-3[Co(CN)(6)](2) hybrid nanoparticles: preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions.DALTON TRANSACTIONS,45(2),539-544. |
| MLA | Li, Ren,et al."Pd-Co-3[Co(CN)(6)](2) hybrid nanoparticles: preparation, characterization, and challenge for the Suzuki-Miyaura coupling of aryl chlorides under mild conditions".DALTON TRANSACTIONS 45.2(2016):539-544. |
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