Institutional Repository of Chinese Acad Sci, High Field Magnet Lab,Hefei 230031, Anhui, Peoples R China
Phase transition and critical behavior of spin-orbital coupled spinel ZnV2O4 | |
Wang, Li1,2; Wang, Rong-juan1,2; Zhu, Yuan-yuan3; Lu, Zhi-hong4; Xiong, Rui1,2; Liu, Yong1,2![]() | |
2016 | |
发表期刊 | CHINESE PHYSICS B
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摘要 | We present the temperature-dependent susceptibility and specific heat measurement of spinel ZnV2O4. The structural transition with orbital ordering and the antiferromagnetic transition with spin ordering were observed at 50 K and 37 K, respectively. By analysis of the hysteresis behavior between the specific heat curves obtained in warming and cooling processes, the structural transition was confirmed to be the first-order transition, while the antiferromagnetic transition was found to be of the second-order type. At the structural transition, the latent heat and entropy change were calculated from the excess specific heat, and the derivative of pressure with respect to temperature was obtained using the Clausius-Clapayron equation. At the magnetic transition, the width of the critical fluctuation region was obtained to be about 0.5 K by comparing with Gaussian fluctuations. In the critical region, the critical behavior was analyzed by using renormalization-group theory. The critical amplitude ratio A(+)/A(-) = 1.46, which deviates from the 3D Heisenburg model; while the critical exponent alpha is -0.011, which is close to the 3D XY model. We proposed that these abnormal critical behaviors can be attributed to strong spin-orbital coupling accompanied with the antiferromagnetic transition. Moreover, in the low temperature range (2-5 K), the Fermi energy, the density of states near the Fermi surface, and the low limit of Debye temperature were estimated to be 2.42 eV, 2.48 eV(-1), and 240 K, respectively. |
文章类型 | Article |
关键词 | Spinel Compounds Specific Heat Phase Transition Critical Behavior |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1088/1674-1056/25/1/016802 |
关键词[WOS] | HYDROGEN STORAGE PROPERTIES ; MAGNETIC-PROPERTIES ; HEAT ; SUSCEPTIBILITY |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Basic Research Program of China(2012CB821404) ; National Basic Research Program of China(2012CB821404) ; National Basic Research Program of China(2012CB821404) ; National Basic Research Program of China(2012CB821404) ; National Basic Research Program of China(2012CB821404) ; National Basic Research Program of China(2012CB821404) ; National Basic Research Program of China(2012CB821404) ; National Basic Research Program of China(2012CB821404) ; National Natural Science Foundation of China(51172166 ; National Natural Science Foundation of China(51172166 ; National Natural Science Foundation of China(51172166 ; National Natural Science Foundation of China(51172166 ; National Natural Science Foundation of China(51172166 ; National Natural Science Foundation of China(51172166 ; National Natural Science Foundation of China(51172166 ; National Natural Science Foundation of China(51172166 ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; National Science Fund for Talent Training in Basic Science, China(J1210061) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; Doctoral Fund of Ministry of Education of China(20110141110007) ; 61106005) ; 61106005) ; 61106005) ; 61106005) ; 61106005) ; 61106005) ; 61106005) ; 61106005) |
WOS研究方向 | Physics |
WOS类目 | Physics, Multidisciplinary |
WOS记录号 | WOS:000368455100063 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/22263 |
专题 | 中科院强磁场科学中心 |
作者单位 | 1.Wuhan Univ, Key Lab Artificial Micro & Nanostruct, Minist Educ, Wuhan 430072, Peoples R China 2.Wuhan Univ, Sch Phys & Technol, Wuhan 430072, Peoples R China 3.Chinese Acad Sci, High Field Magnet Lab, Hefei 230031, Peoples R China 4.Wuhan Univ Sci & Technol, Sch Met & Mat, Wuhan 430081, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Li,Wang, Rong-juan,Zhu, Yuan-yuan,et al. Phase transition and critical behavior of spin-orbital coupled spinel ZnV2O4[J]. CHINESE PHYSICS B,2016,25(1):1-6. |
APA | Wang, Li.,Wang, Rong-juan.,Zhu, Yuan-yuan.,Lu, Zhi-hong.,Xiong, Rui.,...&Shi, Jing.(2016).Phase transition and critical behavior of spin-orbital coupled spinel ZnV2O4.CHINESE PHYSICS B,25(1),1-6. |
MLA | Wang, Li,et al."Phase transition and critical behavior of spin-orbital coupled spinel ZnV2O4".CHINESE PHYSICS B 25.1(2016):1-6. |
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