Institutional Repository of Chinese Acad Sci, High Field Magnet Lab,Hefei 230031, Anhui, Peoples R China
| Facile synthesis of MOF-derived ultrafine Co nanocrystals embedded in a nitrogen-doped carbon matrix for the hydrogen evolution reaction | |
| Zheng, Fangcai1,2,3; Xia, Hongyu1; Xu, Shihao1; Wang, Rencui1; Zhang, Yuanguang1 | |
| 2016 | |
| 发表期刊 | RSC ADVANCES
 |
| 摘要 | Non-precious metal-based catalysts with low cost and rich reserves are emerging as promising alternatives for Pt-based catalysts for the hydrogen evolution reaction (HER). Herein, we reported a facile and large-scale strategy for Co nanocrystals embedded in a nitrogen-doped carbon matrix through direct carbonization of Co-based metal-organic frameworks (MOFs) in N-2. After carbonization, the ultrafine Co nanocrystals are well dispersed in the nitrogen-doped carbon matrix. We further studied their electrocatalytic properties toward the HER in acidic media and found that the as-prepared catalyst exhibited enhanced catalytic activity and stability. |
| 文章类型 | Article |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c6ra10020a |
| 关键词[WOS] | LITHIUM ANODIC PERFORMANCE ; METAL-ORGANIC FRAMEWORK ; GRAPHENE ; NANOPARTICLES ; NANOTUBES ; PALLADIUM ; CATALYSIS ; GOLD ; IRON |
| 收录类别 | SCI |
| 语种 | 英语 |
| 项目资助者 | National Natural Science Foundation (NSFC)(21371009) ; National Natural Science Foundation (NSFC)(21371009) ; National Natural Science Foundation (NSFC)(21371009) ; National Natural Science Foundation (NSFC)(21371009) ; Anhui provincial Natural Foundation(1608085QB34) ; Anhui provincial Natural Foundation(1608085QB34) ; Anhui provincial Natural Foundation(1608085QB34) ; Anhui provincial Natural Foundation(1608085QB34) ; Science and Technology Commission of Shanghai Municipality(14DZ2261000) ; Science and Technology Commission of Shanghai Municipality(14DZ2261000) ; Science and Technology Commission of Shanghai Municipality(14DZ2261000) ; Science and Technology Commission of Shanghai Municipality(14DZ2261000) |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Multidisciplinary |
| WOS记录号 | WOS:000381513100120 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/24020 |
| 专题 | 中科院强磁场科学中心 |
| 作者单位 | 1.Anqing Normal Univ, Anhui Key Lab Funct Coordinat Cpds, Sch Chem & Engn, Anqing 246011, Peoples R China 2.Chinese Acad Sci, Hefei Inst Phys Sci, High Magnet Field Lab, Hefei 230031, Peoples R China 3.Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Fangcai,Xia, Hongyu,Xu, Shihao,et al. Facile synthesis of MOF-derived ultrafine Co nanocrystals embedded in a nitrogen-doped carbon matrix for the hydrogen evolution reaction[J]. RSC ADVANCES,2016,6(75):71767-71772. |
| APA | Zheng, Fangcai,Xia, Hongyu,Xu, Shihao,Wang, Rencui,&Zhang, Yuanguang.(2016).Facile synthesis of MOF-derived ultrafine Co nanocrystals embedded in a nitrogen-doped carbon matrix for the hydrogen evolution reaction.RSC ADVANCES,6(75),71767-71772. |
| MLA | Zheng, Fangcai,et al."Facile synthesis of MOF-derived ultrafine Co nanocrystals embedded in a nitrogen-doped carbon matrix for the hydrogen evolution reaction".RSC ADVANCES 6.75(2016):71767-71772. |
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