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Performance of a novelly-defined zirconium metal-organic frameworks adsorption membrane in fluoride removal
He, Junyong1,2; Cai, Xingguo1,2; Chen, Kai1,2; Li, Yulian1,2; Zhang, Kaisheng1; Jin, Zhen1; Meng, Fanli1; Liu, Ning3; Wang, Xuguang4; Kong, Lingtao1; Huang, Xingjiu1; Liu, Jinhuai1
2016-12-15
Source PublicationJOURNAL OF COLLOID AND INTERFACE SCIENCE
AbstractA novelly-defined adsorption membrane for rapid removal of fluoride from drinking water was prepared. Both zirconium metal-organic frameworks (Zr-MOFs) adsorbent and membrane with large specific surface area of 740.28 m(2)/g were used for fluoride removal for the first time. For adsorption technique, fluoride adsorption on Zr-MOFs was studied on a batch mode. The adsorption data could be well described by Langmuir isotherm model while the adsorption kinetic followed pseudo-second-order model. The maximum of adsorption capacity was 102.40 mg/g at pH 7.0 when the initial fluoride concentration was 200 mg/L. The FT-IR and XPS analyses of Zr-MOFs revealed that both surface hydroxyl groups and Zr(IV) active sites played important roles in fluoride adsorption process. The as-prepared Zr-MOFs adsorbent was suitable for practical treatment of drinking water and regeneration by sodium hydroxide solution (3 wt%). For membrane experiments, Zr-MOFs membrane supported on Alumina substrate could remove fluoride efficiently through dynamic filtration. The fluoride removal capability of Zr-MOFs membrane depended on flow rate and initial concentration of fluoride. The fluoride removal abilities of Zr-MOFs membrane with 20 mu m thickness could reach 5510, 5173, and 4664 L/m(2) when fluoride concentrations were 5, 8 and 10 mg/L, respectively. This study indicated that Zr-MOFs membrane could be developed into a very viable technology for highly effective removal of fluoride from drinking water. (C) 2016 Elsevier Inc. All rights reserved.
SubtypeArticle
KeywordZr-mofs Membrane Fluoride Adsorption Mechanism
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.jcis.2016.08.074
WOS KeywordDRINKING-WATER ; AQUEOUS-SOLUTION ; ENHANCED ADSORPTION ; AMBIENT CONDITIONS ; HYDROGEN STORAGE ; LOW-COST ; MOFS ; HYDROXYAPATITE ; DEFLUORIDATION ; ADSORBENT
Indexed BySCI
Language英语
Funding OrganizationNational Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Natural Science Foundation of China(21277146 ; National Natural Science Foundation of China(21277146 ; National Natural Science Foundation of China(21277146 ; National Natural Science Foundation of China(21277146 ; Key Technologies R&D Program of Anhui Province(1501021005) ; Key Technologies R&D Program of Anhui Province(1501021005) ; Key Technologies R&D Program of Anhui Province(1501021005) ; Key Technologies R&D Program of Anhui Province(1501021005) ; 21177131 ; 21177131 ; 21177131 ; 21177131 ; 61273066 ; 61273066 ; 61273066 ; 61273066 ; 11205204 ; 11205204 ; 11205204 ; 11205204 ; 21105001 ; 21105001 ; 21105001 ; 21105001 ; 21077106 ; 21077106 ; 21077106 ; 21077106 ; 61104205) ; 61104205) ; 61104205) ; 61104205)
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000385690200019
Citation statistics
Cited Times:77[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/30128
Collection中科院合肥智能机械研究所
Affiliation1.Chinese Acad Sci, Hefei Inst Intelligent Machines, Nanomat & Environm Detect Lab, Hefei 230031, Anhui, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
3.Anui Polytech Univ, Wuhu 233500, Anhui, Peoples R China
4.Mengcheng Water Affair Bur, Mengcheng 233500, Anhui, Peoples R China
Recommended Citation
GB/T 7714
He, Junyong,Cai, Xingguo,Chen, Kai,et al. Performance of a novelly-defined zirconium metal-organic frameworks adsorption membrane in fluoride removal[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2016,484(无):162-172.
APA He, Junyong.,Cai, Xingguo.,Chen, Kai.,Li, Yulian.,Zhang, Kaisheng.,...&Liu, Jinhuai.(2016).Performance of a novelly-defined zirconium metal-organic frameworks adsorption membrane in fluoride removal.JOURNAL OF COLLOID AND INTERFACE SCIENCE,484(无),162-172.
MLA He, Junyong,et al."Performance of a novelly-defined zirconium metal-organic frameworks adsorption membrane in fluoride removal".JOURNAL OF COLLOID AND INTERFACE SCIENCE 484.无(2016):162-172.
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