Institutional Repository of Chinese Acad Sci, Hefei Inst Phys Sci, Inst Appl Technol，Hefei 230031, Anhui, Peoples R China
| Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells | |
Liu, Shi-Dong1; Ren, Ying-Ke1; Zhou, Zheng1; Chen, Wang-Chao2; Li, Zhao-Qian2 ; Guo, Fu-Ling2; Mo, Li-E2; Wu, Ji-Huai3; Hu, Lin-Hua2; Dai, Song-Yuan1,2
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| 2016-10-15 | |
| Source Publication | JOURNAL OF POWER SOURCES
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| Abstract | This paper describes a facile solvothermal method to synthesize TiO2 microspheres by employing ethylene glycol monomethyl ether and ethylene glycol as solvent. By analyzing the resulted supernatant after reaction, it was proved that the etherification reaction of glycol monomethyl ether and the ligand exchange between ethylene glycol and tetra-n-butyl titanate played a key role in synthesis of TiO2 microspheres. These as-obtained TiO2 microspheres exhibited high specific surface area up to 113.24 m(2) g(-1) and have a narrow pore size distribution (6.94 nm). When applied to the photoanode, the TiO2 microsphere-based dye-sensitized solar cells achieved a high power conversion efficiency up to 10.25%. (C) 2016 Elsevier B.V. All rights reserved. |
| Subtype | Article |
| Keyword | Tio2 Microspheres Ethylene Glycol Monomethyl Ether Etherification Reaction Ligand Exchange |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1016/j.jpowsour.2016.08.090 |
| WOS Keyword | LONG CYCLE CAPABILITY ; HIGH SURFACE-AREAS ; ONE-POT SYNTHESIS ; PHOTOCATALYTIC ACTIVITY ; TITANIA SPHERES ; HOLLOW SPHERES ; HIGH-CAPACITY ; PORE SIZES ; BEADS ; NANOSTRUCTURES |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; U1205112 ; U1205112 ; U1205112 ; U1205112 ; 21273242) ; 21273242) ; 21273242) ; 21273242) |
| WOS Research Area | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| WOS Subject | Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000384852800024 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.hfcas.ac.cn:8080/handle/334002/30166 |
| Collection | 应用技术研究所 |
| Affiliation | 1.North China Elect Power Univ, Beijing Key Lab Novel Thin Film Solar Cells, Beijing 102206, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Novel Thin Film Solar Cells, Inst Appl Technol, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China 3.Huaqiao Univ, Inst Mat Phys Chem, Quanzhou 362021, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Shi-Dong,Ren, Ying-Ke,Zhou, Zheng,et al. Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells[J]. JOURNAL OF POWER SOURCES,2016,329(无):225-231. |
| APA | Liu, Shi-Dong.,Ren, Ying-Ke.,Zhou, Zheng.,Chen, Wang-Chao.,Li, Zhao-Qian.,...&Dai, Song-Yuan.(2016).Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells.JOURNAL OF POWER SOURCES,329(无),225-231. |
| MLA | Liu, Shi-Dong,et al."Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells".JOURNAL OF POWER SOURCES 329.无(2016):225-231. |
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