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Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells
Liu, Shi-Dong1; Ren, Ying-Ke1; Zhou, Zheng1; Chen, Wang-Chao2; Li, Zhao-Qian2; Guo, Fu-Ling2; Mo, Li-E2; Wu, Ji-Huai3; Hu, Lin-Hua2; Dai, Song-Yuan1,2
2016-10-15
发表期刊JOURNAL OF POWER SOURCES
摘要This paper describes a facile solvothermal method to synthesize TiO2 microspheres by employing ethylene glycol monomethyl ether and ethylene glycol as solvent. By analyzing the resulted supernatant after reaction, it was proved that the etherification reaction of glycol monomethyl ether and the ligand exchange between ethylene glycol and tetra-n-butyl titanate played a key role in synthesis of TiO2 microspheres. These as-obtained TiO2 microspheres exhibited high specific surface area up to 113.24 m(2) g(-1) and have a narrow pore size distribution (6.94 nm). When applied to the photoanode, the TiO2 microsphere-based dye-sensitized solar cells achieved a high power conversion efficiency up to 10.25%. (C) 2016 Elsevier B.V. All rights reserved.
文章类型Article
关键词Tio2 Microspheres Ethylene Glycol Monomethyl Ether Etherification Reaction Ligand Exchange
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jpowsour.2016.08.090
关键词[WOS]LONG CYCLE CAPABILITY ; HIGH SURFACE-AREAS ; ONE-POT SYNTHESIS ; PHOTOCATALYTIC ACTIVITY ; TITANIA SPHERES ; HOLLOW SPHERES ; HIGH-CAPACITY ; PORE SIZES ; BEADS ; NANOSTRUCTURES
收录类别SCI
语种英语
项目资助者National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; U1205112 ; U1205112 ; U1205112 ; U1205112 ; 21273242) ; 21273242) ; 21273242) ; 21273242)
WOS研究方向Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
WOS类目Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号WOS:000384852800024
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/30166
专题应用技术研究所
作者单位1.North China Elect Power Univ, Beijing Key Lab Novel Thin Film Solar Cells, Beijing 102206, Peoples R China
2.Chinese Acad Sci, Beijing Key Lab Novel Thin Film Solar Cells, Inst Appl Technol, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China
3.Huaqiao Univ, Inst Mat Phys Chem, Quanzhou 362021, Peoples R China
推荐引用方式
GB/T 7714
Liu, Shi-Dong,Ren, Ying-Ke,Zhou, Zheng,et al. Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells[J]. JOURNAL OF POWER SOURCES,2016,329(无):225-231.
APA Liu, Shi-Dong.,Ren, Ying-Ke.,Zhou, Zheng.,Chen, Wang-Chao.,Li, Zhao-Qian.,...&Dai, Song-Yuan.(2016).Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells.JOURNAL OF POWER SOURCES,329(无),225-231.
MLA Liu, Shi-Dong,et al."Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells".JOURNAL OF POWER SOURCES 329.无(2016):225-231.
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