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Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells
Liu, Shi-Dong1; Ren, Ying-Ke1; Zhou, Zheng1; Chen, Wang-Chao2; Li, Zhao-Qian2; Guo, Fu-Ling2; Mo, Li-E2; Wu, Ji-Huai3; Hu, Lin-Hua2; Dai, Song-Yuan1,2
2016-10-15
Source PublicationJOURNAL OF POWER SOURCES
AbstractThis paper describes a facile solvothermal method to synthesize TiO2 microspheres by employing ethylene glycol monomethyl ether and ethylene glycol as solvent. By analyzing the resulted supernatant after reaction, it was proved that the etherification reaction of glycol monomethyl ether and the ligand exchange between ethylene glycol and tetra-n-butyl titanate played a key role in synthesis of TiO2 microspheres. These as-obtained TiO2 microspheres exhibited high specific surface area up to 113.24 m(2) g(-1) and have a narrow pore size distribution (6.94 nm). When applied to the photoanode, the TiO2 microsphere-based dye-sensitized solar cells achieved a high power conversion efficiency up to 10.25%. (C) 2016 Elsevier B.V. All rights reserved.
SubtypeArticle
KeywordTio2 Microspheres Ethylene Glycol Monomethyl Ether Etherification Reaction Ligand Exchange
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jpowsour.2016.08.090
WOS KeywordLONG CYCLE CAPABILITY ; HIGH SURFACE-AREAS ; ONE-POT SYNTHESIS ; PHOTOCATALYTIC ACTIVITY ; TITANIA SPHERES ; HOLLOW SPHERES ; HIGH-CAPACITY ; PORE SIZES ; BEADS ; NANOSTRUCTURES
Indexed BySCI
Language英语
Funding OrganizationNational High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; National High Technology Research and Development Program of China(2015AA050602) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; External Cooperation Program of BIS, Chinese Academy of Sciences(GJHZ1607) ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; National Natural Science Foundation of China(51572080 ; U1205112 ; U1205112 ; U1205112 ; U1205112 ; 21273242) ; 21273242) ; 21273242) ; 21273242)
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels ; Materials Science
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000384852800024
Citation statistics
Cited Times:9[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/30166
Collection应用技术研究所
Affiliation1.North China Elect Power Univ, Beijing Key Lab Novel Thin Film Solar Cells, Beijing 102206, Peoples R China
2.Chinese Acad Sci, Beijing Key Lab Novel Thin Film Solar Cells, Inst Appl Technol, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China
3.Huaqiao Univ, Inst Mat Phys Chem, Quanzhou 362021, Peoples R China
Recommended Citation
GB/T 7714
Liu, Shi-Dong,Ren, Ying-Ke,Zhou, Zheng,et al. Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells[J]. JOURNAL OF POWER SOURCES,2016,329(无):225-231.
APA Liu, Shi-Dong.,Ren, Ying-Ke.,Zhou, Zheng.,Chen, Wang-Chao.,Li, Zhao-Qian.,...&Dai, Song-Yuan.(2016).Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells.JOURNAL OF POWER SOURCES,329(无),225-231.
MLA Liu, Shi-Dong,et al."Synthesis of TiO2 microspheres building on the etherification and its application for high efficiency solar cells".JOURNAL OF POWER SOURCES 329.无(2016):225-231.
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