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Performance of novel hydroxyapatite nanowires in treatment of fluoride contaminated water
He, Junyong1,2; Zhang, Kaisheng1,2; Wu, Shibiao1; Cai, Xingguo1,2; Chen, Kai1,2; Li, Yulian1,2; Sun, Bai1; Jia, Yong1; Meng, Fanli1; Jin, Zhen1; Kong, Lingtao1; Liu, Jinhuai1
2016-02-13
发表期刊JOURNAL OF HAZARDOUS MATERIALS
摘要Novel ultralong hydroxyapatite (HAP) nanowires were successfully prepared for fluoride removal for the first time. The fluoride adsorption on the HAP nanowires was studied on a batch mode. The results revealed that the adsorption data could be well described by the Freundlich model, and the adsorption kinetic followed the pseudo-second-order model. The maximum of adsorption capacity was 40.65 mg/g at pH 7.0 when the fluoride concentration is 200 mg/L. The thermodynamic parameters suggested that the adsorption of fluoride was a spontaneous endothermic process. The FT-IR, XPS and Zeta potential analysis revealed that both anion exchange and electrostatic interactions were involved in the adsorption of fluoride. Furthermore, the HAP nanowires were made into HAP membrane through a simple process of suction filtration. Membrane filtration experiments revealed that the fluoride removal capabilities depended on the membrane thickness, flow rate and initial concentration of fluoride. The as-prepared membrane could remove fluoride efficiently through continues filtration. The filtered water amount could reach 350, 192, and 64 L/m(2) when the fluoride concentrations were 4, 5 and 8 ppm, respectively, using the HAP membrane with only 150 pm thickness. The as-synthesized ultralong HAP nanowires were thus demonstrated to be very effective and biocompatible adsorbents for fluoride removal from contaminated water. (C) 2015 Elsevier B.V. All rights reserved.
文章类型Article
关键词Hydroxyapatite Nanowires Membrane Fluoride Adsorption
WOS标题词Science & Technology ; Technology ; Life Sciences & Biomedicine
DOI10.1016/j.jhazmat.2015.10.028
关键词[WOS]DRINKING-WATER ; AQUEOUS-SOLUTION ; DOPED HYDROXYAPATITE ; REMOVAL PERFORMANCE ; ENHANCED ADSORPTION ; SYNTHETIC HYDROXYAPATITE ; BONE CHAR ; NANOPARTICLES ; SORPTION ; IONS
收录类别SCI
语种英语
项目资助者National Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Key Scientific Program-Nanoscience and Nanotechnology(2011CB933700) ; National Natural Science Foundation of China(21177131 ; National Natural Science Foundation of China(21177131 ; National Natural Science Foundation of China(21177131 ; National Natural Science Foundation of China(21177131 ; Key Technologies R & D Program of Anhui Province(1501021005) ; Key Technologies R & D Program of Anhui Province(1501021005) ; Key Technologies R & D Program of Anhui Province(1501021005) ; Key Technologies R & D Program of Anhui Province(1501021005) ; 21277146 ; 21277146 ; 21277146 ; 21277146 ; 61273066 ; 61273066 ; 61273066 ; 61273066 ; 11205204 ; 11205204 ; 11205204 ; 11205204 ; 61374017) ; 61374017) ; 61374017) ; 61374017)
WOS研究方向Engineering ; Environmental Sciences & Ecology
WOS类目Engineering, Environmental ; Engineering, Civil ; Environmental Sciences
WOS记录号WOS:000366954600014
引用统计
被引频次:121[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/30212
专题中科院合肥智能机械研究所
作者单位1.Chinese Acad Sci, Inst Intelligent Machines, Nanomat & Environm Detect Lab, Hefei 230031, Peoples R China
2.Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
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He, Junyong,Zhang, Kaisheng,Wu, Shibiao,et al. Performance of novel hydroxyapatite nanowires in treatment of fluoride contaminated water[J]. JOURNAL OF HAZARDOUS MATERIALS,2016,303(无):119-130.
APA He, Junyong.,Zhang, Kaisheng.,Wu, Shibiao.,Cai, Xingguo.,Chen, Kai.,...&Liu, Jinhuai.(2016).Performance of novel hydroxyapatite nanowires in treatment of fluoride contaminated water.JOURNAL OF HAZARDOUS MATERIALS,303(无),119-130.
MLA He, Junyong,et al."Performance of novel hydroxyapatite nanowires in treatment of fluoride contaminated water".JOURNAL OF HAZARDOUS MATERIALS 303.无(2016):119-130.
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