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In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy
Zhang, Ji1,2; Wang, Di3,4; Zhang, Deming2; Zhang, Qingli2; Sun, Dunlu2; Yin, Shaotang2
2017-06-15
发表期刊JOURNAL OF MOLECULAR STRUCTURE
卷号1138页码:50-54
摘要High-temperature Raman spectroscopy has been applied to investigate in situ the solution structure near the BaBPO5 crystal-solution interface. The experimental results show that [P2O7] and [BO4] are the basic structural units in BaBPO5-Li4P2O7 high temperature solution, and [BPO7] is the main growth unit of BaBPO5 crystal. In the crystal growth boundary layer, the [P2O7] and [BO4] units are transformed into [BPO7] unit. BaBPO5 crystal growth process is considered as a connection process of growth unit [BPO7] along c axis direction. According to the mechanism, the growth habits of BaBPO5 crystal can be predicted. (C) 2017 Published by Elsevier B.V.
文章类型Article
关键词Babpo5 Crystal Raman Spectra Crystal Growth Molecular Structure
WOS标题词Science & Technology ; Physical Sciences
资助者Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239) ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239)
DOI10.1016/j.molstruc.2017.01.029
关键词[WOS]SINGLE-CRYSTAL ; BOUNDARY-LAYER ; GLASSES ; MICROSTRUCTURE ; BOROPHOSPHATE ; LUMINESCENCE ; SPECTRUM ; KTIOPO4 ; SYSTEM ; CE3+
收录类别SCI
语种英语
资助者Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239) ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239)
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000399517500008
引用统计
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/33512
专题中科院安徽光学精密机械研究所
作者单位1.Anhui Xin Hua Univ, Hefei 230088, Peoples R China
2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
3.Nanjing Univ, Natl Lab Solid State Microstruct, Dept Phys, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
4.Tianjin Univ Technol, Sch Mat Sci & Engn, Tianjin 300384, Peoples R China
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GB/T 7714
Zhang, Ji,Wang, Di,Zhang, Deming,et al. In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy[J]. JOURNAL OF MOLECULAR STRUCTURE,2017,1138:50-54.
APA Zhang, Ji,Wang, Di,Zhang, Deming,Zhang, Qingli,Sun, Dunlu,&Yin, Shaotang.(2017).In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy.JOURNAL OF MOLECULAR STRUCTURE,1138,50-54.
MLA Zhang, Ji,et al."In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy".JOURNAL OF MOLECULAR STRUCTURE 1138(2017):50-54.
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