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In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy
Zhang, Ji1,2; Wang, Di3,4; Zhang, Deming2; Zhang, Qingli2; Sun, Dunlu2; Yin, Shaotang2
2017-06-15
Source PublicationJOURNAL OF MOLECULAR STRUCTURE
Volume1138Pages:50-54
AbstractHigh-temperature Raman spectroscopy has been applied to investigate in situ the solution structure near the BaBPO5 crystal-solution interface. The experimental results show that [P2O7] and [BO4] are the basic structural units in BaBPO5-Li4P2O7 high temperature solution, and [BPO7] is the main growth unit of BaBPO5 crystal. In the crystal growth boundary layer, the [P2O7] and [BO4] units are transformed into [BPO7] unit. BaBPO5 crystal growth process is considered as a connection process of growth unit [BPO7] along c axis direction. According to the mechanism, the growth habits of BaBPO5 crystal can be predicted. (C) 2017 Published by Elsevier B.V.
SubtypeArticle
KeywordBabpo5 Crystal Raman Spectra Crystal Growth Molecular Structure
WOS HeadingsScience & Technology ; Physical Sciences
Funding OrganizationNatural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239) ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239)
DOI10.1016/j.molstruc.2017.01.029
WOS KeywordSINGLE-CRYSTAL ; BOUNDARY-LAYER ; GLASSES ; MICROSTRUCTURE ; BOROPHOSPHATE ; LUMINESCENCE ; SPECTRUM ; KTIOPO4 ; SYSTEM ; CE3+
Indexed BySCI
Language英语
Funding OrganizationNatural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239) ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of China(51302268 ; Natural Science Foundation of Anhui Province(KJ2015A339) ; Natural Science Foundation of Anhui Province(KJ2015A339) ; 51102239) ; 51102239)
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000399517500008
Citation statistics
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/33512
Collection中科院安徽光学精密机械研究所
Affiliation1.Anhui Xin Hua Univ, Hefei 230088, Peoples R China
2.Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Hefei 230031, Peoples R China
3.Nanjing Univ, Natl Lab Solid State Microstruct, Dept Phys, Collaborat Innovat Ctr Adv Microstruct, Nanjing 210093, Jiangsu, Peoples R China
4.Tianjin Univ Technol, Sch Mat Sci & Engn, Tianjin 300384, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Ji,Wang, Di,Zhang, Deming,et al. In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy[J]. JOURNAL OF MOLECULAR STRUCTURE,2017,1138:50-54.
APA Zhang, Ji,Wang, Di,Zhang, Deming,Zhang, Qingli,Sun, Dunlu,&Yin, Shaotang.(2017).In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy.JOURNAL OF MOLECULAR STRUCTURE,1138,50-54.
MLA Zhang, Ji,et al."In situ investigation of BaBPO5 crystal growth mechanism by high-temperature Raman spectroscopy".JOURNAL OF MOLECULAR STRUCTURE 1138(2017):50-54.
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