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Surface Modification of Fluorine-containing Polymers by Atmospheric Pressure Plasma Jet with Negative Substrate Biasing
Nagatsu, Masaaki1,2,3; Kimpara, Masahiro2; Hu, Rui3,4; Abuzairi, Tomy5
2017
发表期刊JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY
卷号30期号:3页码:307-312
摘要Fluoropolymers are difficult materials to modify the surfaces because of strong C-F bonds. In this study, the surface modification of fluoropolymer films such as polytetrafluoroethylene (PTFE) with amino groups was performed by using He/NH3 gas mixture atmospheric pressure plasma jets with negatively-biased substrate. It is expected that the ion bombardment effect onto the polymer surface due to negative substrate bias will make dangling bonds over the polymer surface and eventually promote the surface modification. From XPS analysis, we confirmed the breaking C-F bonds and creating C-C, C=O or C-N bonds in C ls spectrum and increasing nitrogen-containing functional groups in N ls spectrum. Fluorescence patterns were observed on the amino group functionalized PTFE surface by using the fluorescent dyes selectively connecting with the amino groups. With a spectrophotometric method, the surface concentration of amino groups introduced onto the PTFE surface was evaluated to be roughly 1.93 nmol/cm(2).
文章类型Article
关键词Surface Modification Fluoropolymers Polytetrafluoroethylene Atmospheric Pressure Plasma Jet Amino Group
WOS标题词Science & Technology ; Physical Sciences
资助者Japan Society for the Promotion of Science(21110010 ; Japan Society for the Promotion of Science(21110010 ; 25246029) ; 25246029) ; Japan Society for the Promotion of Science(21110010 ; Japan Society for the Promotion of Science(21110010 ; 25246029) ; 25246029)
关键词[WOS]POLYTETRAFLUOROETHYLENE FILMS ; PTFE ; ADHESION ; FUNCTIONALIZATION
收录类别SCI
语种英语
资助者Japan Society for the Promotion of Science(21110010 ; Japan Society for the Promotion of Science(21110010 ; 25246029) ; 25246029) ; Japan Society for the Promotion of Science(21110010 ; Japan Society for the Promotion of Science(21110010 ; 25246029) ; 25246029)
WOS研究方向Polymer Science
WOS类目Polymer Science
WOS记录号WOS:000407658300010
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/33575
专题中科院等离子体物理研究所
作者单位1.Shizuoka Univ, Res Inst Elect, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328561, Japan
2.Shizuoka Univ, Grad Sch Integrated Sci & Technol, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328561, Japan
3.Shizuoka Univ, Grad Sch Sci & Technol, Naka Ku, 3-5-1 Johoku, Hamamatsu, Shizuoka 4328561, Japan
4.Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Anhui, Peoples R China
5.Univ Indonesia, Dept Elect Engn, Depok 16424, Indonesia
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Nagatsu, Masaaki,Kimpara, Masahiro,Hu, Rui,et al. Surface Modification of Fluorine-containing Polymers by Atmospheric Pressure Plasma Jet with Negative Substrate Biasing[J]. JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY,2017,30(3):307-312.
APA Nagatsu, Masaaki,Kimpara, Masahiro,Hu, Rui,&Abuzairi, Tomy.(2017).Surface Modification of Fluorine-containing Polymers by Atmospheric Pressure Plasma Jet with Negative Substrate Biasing.JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY,30(3),307-312.
MLA Nagatsu, Masaaki,et al."Surface Modification of Fluorine-containing Polymers by Atmospheric Pressure Plasma Jet with Negative Substrate Biasing".JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY 30.3(2017):307-312.
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