Institutional Repository of Chinese Acad Sci, High Field Magnet Lab,Hefei 230031, Anhui, Peoples R China
Tunable inverted gap in monolayer quasi-metallic MoS2 induced by strong charge-lattice coupling | |
Yin, Xinmao1,2,3; Wang, Qixing2; Cao, Liang2,4; Tang, Chi Sin2,5; Luo, Xin2,6,7,8; Zheng, Yujie2; Wong, Lai Mun9; Wang, Shi Jie9; Quek, Su Ying2,6,7; Zhang, Wenjing1; Rusydi, Andrivo2,3,5,10; Wee, Andrew T. S.2,5,6,7 | |
2017-09-07 | |
发表期刊 | NATURE COMMUNICATIONS |
摘要 | Polymorphism of two-dimensional transition metal dichalcogenides such as molybdenum disulfide (MoS2) exhibit fascinating optical and transport properties. Here, we observe a tunable inverted gap (similar to 0.50 eV) and a fundamental gap (similar to 0.10 eV) in quasimetallic monolayer MoS2. Using spectral-weight transfer analysis, we find that the inverted gap is attributed to the strong charge-lattice coupling in two-dimensional transition metal dichalcogenides ( 2D-TMDs). A comprehensive experimental study, supported by theoretical calculations, is conducted to understand the transition of monolayer MoS2 on gold film from trigonal semiconducting 1H phase to the distorted octahedral quasimetallic 1T' phase. We clarify that electron doping from gold, facilitated by interfacial tensile strain, is the key mechanism leading to its 1H-1T' phase transition, thus resulting in the formation of the inverted gap. Our result shows the importance of charge-lattice coupling to the intrinsic properties of the inverted gap and polymorphism of MoS2, thereby unlocking new possibilities for 2D-TMD-based device fabrication. |
文章类型 | Article |
WOS标题词 | Science & Technology |
DOI | 10.1038/s41467-017-00640-2 |
关键词[WOS] | LAYER MOLYBDENUM-DISULFIDE ; CHEMICAL-VAPOR-DEPOSITION ; PHASE-TRANSITION ; ELECTRONIC-STRUCTURE ; ATOMIC LAYERS ; THIN-FILMS ; MOTE2 ; SUPERCONDUCTIVITY ; HETEROSTRUCTURES ; DICHALCOGENIDES |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; National Natural Science Foundation of China(51472164) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; Natural Science Foundation of SZU(000050) ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; 1000 Talents Program for Young Scientists of China ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Shenzhen Peacock Plan(KQTD2016053112042971) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Educational Commission of Guangdong Province(2015KGJHZ006) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; Science and Technology Planning Project of Guangdong Province(2016B050501005) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; China Postdoctoral Science Foundation(2016M600664) ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; Singapore National Research Foundation(NRF-CRP8-2011-06 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; MOE(MOE2015-T2-1-099 ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; PHC Merlion Project ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; FRC(R-144-000-368-112 ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; NRF-CRP15-2015-01) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; MOE2015-T2-2-147) ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-346-112 ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) ; R-144-000-364-112) |
WOS研究方向 | Science & Technology - Other Topics |
WOS类目 | Multidisciplinary Sciences |
WOS记录号 | WOS:000409997500020 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/33701 |
专题 | 中科院强磁场科学中心 |
作者单位 | 1.Shenzhen Univ, SZU NUS Collaborat Innovat Ctr Optoelect Sci & Te, Key Lab Optoelect Devices & Syst, Minist Educ & Guangdong Prov,Coll Optoelect Engn, Shenzhen 518060, Peoples R China 2.Natl Univ Singapore, Dept Phys, Fac Sci, Singapore 117542, Singapore 3.Natl Univ Singapore, SSLS, Singapore 117603, Singapore 4.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme, High Field Magnet Lab, Hefei 230031, Anhui, Peoples R China 5.Natl Univ Singapore, NUS Grad Sch Integrat Sci & Engn, Singapore 117456, Singapore 6.Natl Univ Singapore, Ctr Adv Mat 2D, Singapore 117551, Singapore 7.Natl Univ Singapore, Graphene Res Ctr, Singapore 117551, Singapore 8.Hong Kong Polytech Univ, Dept Appl Phys, Kowloon 999077, Hong Kong, Peoples R China 9.ASTAR, IMRE, 2 Fusionopolis Way, Innovis 138634, Singapore 10.Natl Univ Singapore, NUSNNI NanoCore, Singapore 117576, Singapore |
推荐引用方式 GB/T 7714 | Yin, Xinmao,Wang, Qixing,Cao, Liang,et al. Tunable inverted gap in monolayer quasi-metallic MoS2 induced by strong charge-lattice coupling[J]. NATURE COMMUNICATIONS,2017,8. |
APA | Yin, Xinmao.,Wang, Qixing.,Cao, Liang.,Tang, Chi Sin.,Luo, Xin.,...&Wee, Andrew T. S..(2017).Tunable inverted gap in monolayer quasi-metallic MoS2 induced by strong charge-lattice coupling.NATURE COMMUNICATIONS,8. |
MLA | Yin, Xinmao,et al."Tunable inverted gap in monolayer quasi-metallic MoS2 induced by strong charge-lattice coupling".NATURE COMMUNICATIONS 8(2017). |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论