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Phase engineering of cobalt hydroxides using magnetic fields for enhanced supercapacitor performance
Dai, Peng1; Yan, Taotao1; Hu, Lin2; Pang, Zhanwen1; Bao, Zhiwei1; Wu, Mingzai1; Li, Guang1; Fang, Jun2; Peng, Zhenmeng3
2017-09-28
发表期刊JOURNAL OF MATERIALS CHEMISTRY A
摘要We report on the selective synthesis of single crystal sheet-like alpha-Co(OH)(2) and raft-like nanostructures of beta-Co(OH)(2) hydrothermally using hydrazine as a reducing agent. alpha-Co(OH)(2) sheets of several micrometers in width and about 20 nm in thickness were reproducibly yielded in the presence of an applied strong magnetic field (2 tesla) at 180 degrees C. In the absence of a magnetic field, raft-like nanostructures were obtained, composed of rod-like beta-Co(OH)(2) with a length of about 1.5 mu m. The applied magnetic field was believed to provide a phase transition driving force and promote the phase transition from beta-Co(OH)(2) to alpha-Co(OH)(2). When evaluated as an electrode material for supercapacitors, the as-obtained sheet-like a-Co(OH)(2) exhibited higher capacitance and better cycling stability than beta-Co(OH)(2) prepared in the absence of a magnetic field.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1039/c7ta03656f
关键词[WOS]LITHIUM-ION BATTERIES ; HYDROTHERMAL SYNTHESIS ; ANODE MATERIAL ; ELECTROCHEMICAL PROPERTIES ; ELECTRODE MATERIALS ; PSEUDOCAPACITORS ; MORPHOLOGY ; NANOSHEETS ; NANOWIRES ; DIFFUSION
收录类别SCI
语种英语
项目资助者National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Key R&D Program of China(2017YFA0403600) ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; National Natural Science Foundation of China(11374013 ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Outstanding young talent fund of Anhui Province(J05201424) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; Research Fund for the Doctoral Program of Higher Education of China(20133401110002) ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51672001 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 51502002 ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178) ; 21301178)
WOS研究方向Chemistry ; Energy & Fuels ; Materials Science
WOS类目Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号WOS:000411232100032
引用统计
被引频次:39[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/33750
专题中科院强磁场科学中心
作者单位1.Anhui Univ, Sch Phys & Mat Sci, Hefei 230601, Anhui, Peoples R China
2.Chinese Acad Sci, Anhui Prov Key Lab Condensed Matter Phys Extreme, High Field Magnet Lab, Hefei 230031, Anhui, Peoples R China
3.Univ Akron, Dept Chem & Biomol Engn, Akron, OH 44325 USA
推荐引用方式
GB/T 7714
Dai, Peng,Yan, Taotao,Hu, Lin,et al. Phase engineering of cobalt hydroxides using magnetic fields for enhanced supercapacitor performance[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(36):19203-19209.
APA Dai, Peng.,Yan, Taotao.,Hu, Lin.,Pang, Zhanwen.,Bao, Zhiwei.,...&Peng, Zhenmeng.(2017).Phase engineering of cobalt hydroxides using magnetic fields for enhanced supercapacitor performance.JOURNAL OF MATERIALS CHEMISTRY A,5(36),19203-19209.
MLA Dai, Peng,et al."Phase engineering of cobalt hydroxides using magnetic fields for enhanced supercapacitor performance".JOURNAL OF MATERIALS CHEMISTRY A 5.36(2017):19203-19209.
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