HFCAS OpenIR  > 中科院固体物理研究所
High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries
Liu, Shengwen1; Zhang, Xian1,2; Wang, Guozhong1; Zhang, Yunxia1; Zhang, Haimin1
2017-10-04
发表期刊ACS APPLIED MATERIALS & INTERFACES
卷号9期号:39页码:34269-34278
摘要Developing bifunctional oxygen electrocatalysts with superior catalytic activities of oxygen reduction reaction (ORR) and oxygen revolution reaction (OER) is crucial to their practical energy storage and conversion applications. In this work, we report the fabrication of Co/CoxSy@S,N-codoped porous carbon structures with various morphologies, specific surface areas, and pore structures, derived from controllably grown Co-based metalorganic frameworks with S- and N-containing organic ligands (thiophene-2,5-dicarboxylate, Tdc; and 4,4 '-bipyridine, bpy) utilizing solvent effect (e.g., water and methanol) under room temperature and hydrothermal conditions. The results demonstrate that Co/CoxSy@S,N-codoped carbon fibers fabricated at a pyrolytic temperature of 800 degrees C (Co/CoxSy@SNCF-800) from Co-MOFs fibers fabricated in methanol under hydrothermal conditions as electrocatalysts exhibit superior bifunctional ORR and OER activities in alkaline media, endowing them as air cathodic catalysts in rechargeable zincair batteries with high power density and good durability.
文章类型Article
关键词[Co(Tdc)(Bpy)](n) Solvent Effect Bifunctional Oxygen Electrocatalysts s Zn-air Battery n Dual Organic Ligands
WOS标题词Science & Technology ; Technology
资助者National Natural Science Foundation of China(51672277) ; CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; National Natural Science Foundation of China(51672277) ; CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China
DOI10.1021/acsami.7b11101
关键词[WOS]METAL-ORGANIC FRAMEWORK ; OXYGEN REDUCTION REACTION ; BIFUNCTIONAL ELECTROCATALYSTS ; EVOLUTION REACTIONS ; HIGH-PERFORMANCE ; HYDROGEN EVOLUTION ; FREE CATALYSTS ; SULFIDE ; NANOCOMPOSITES ; NANOPARTICLES
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(51672277) ; CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China ; National Natural Science Foundation of China(51672277) ; CAS ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China
WOS研究方向Science & Technology - Other Topics ; Materials Science
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号WOS:000412717600102
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.hfcas.ac.cn:8080/handle/334002/33791
专题中科院固体物理研究所
作者单位1.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys,Ctr Environm & Energy Nanomat, Hefei 230031, Anhui, Peoples R China
2.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Liu, Shengwen,Zhang, Xian,Wang, Guozhong,et al. High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(39):34269-34278.
APA Liu, Shengwen,Zhang, Xian,Wang, Guozhong,Zhang, Yunxia,&Zhang, Haimin.(2017).High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries.ACS APPLIED MATERIALS & INTERFACES,9(39),34269-34278.
MLA Liu, Shengwen,et al."High-Efficiency Co/CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries".ACS APPLIED MATERIALS & INTERFACES 9.39(2017):34269-34278.
条目包含的文件 下载所有文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
High-Efficiency Co_C(7047KB)期刊论文作者接受稿开放获取CC BY-NC-SA浏览 下载
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Liu, Shengwen]的文章
[Zhang, Xian]的文章
[Wang, Guozhong]的文章
百度学术
百度学术中相似的文章
[Liu, Shengwen]的文章
[Zhang, Xian]的文章
[Wang, Guozhong]的文章
必应学术
必应学术中相似的文章
[Liu, Shengwen]的文章
[Zhang, Xian]的文章
[Wang, Guozhong]的文章
相关权益政策
暂无数据
收藏/分享
文件名: High-Efficiency Co_CoxSy@S,N-Codoped Porous Carbon Electrocatalysts Fabricated from Controllably Grown Sulfur- and Nitrogen-Including Cobalt-Based MOFs for Rechargeable Zinc-Air Batteries.pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。