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Refreshing Piezoelectrics: Distinctive Role of Manganese in Lead Free Perovskites
Yao, Fang-Zhou1,2; Zhang, Mao-Hua1; Wang, Ke1; Zhou, Jia-Jun5; Chen, Feng6; Xu, Bin7,8; Li, Fei3,4; Shen, Yang1; Zhang, Qing-Hua9,10; Gu, Lin9,10; Zhang, Xiao-Wen1; Li, Jing-Feng1
2018-10-31
Source PublicationACS APPLIED MATERIALS & INTERFACES
ISSN1944-8244
Volume10Issue:43Pages:37298-37306
Corresponding AuthorWang, Ke(wang-ke@tsinghua.edu.cn) ; Li, Jing-Feng(jingfeng@mail.tsinghua.edu.cn)
AbstractDriven by an ever-growing demand for environmentally compatible materials, the past two decades have witnessed the booming development in the field of piezoelectrics. To maximally explore the potential of lead-free piezoelectrics, chemical doping could be an effective approach, referenced from tactics adopted in lead-based piezoelectrics. Herein, we reveal the distinct role of manganese in a promising lead-free perovskite (K, Na)NbO3 (denoted by KNN) in comparison to that in market-dominating lead-based counterparts [Pb(Zr, Ti)O-3, PZT]. In contrast to the scenario in PZT, manganese doping in KNN results in tremendously improved piezoelectric coefficient d(33) by nearly 200%, whereas the same doping species in PZT deteriorates the d(33) down to less than 30% of its original value. The result is rationalized from macroscopic and local electrical characterizations down to atomic-scale visualization. This study demonstrates that there is enormous space to further enhance piezoelectricity in lead-free systems because the chemical doping effect may completely differ in lead-containing and lead-free perovskites.
Keyword(K,Na)NbO3 lead free perovskite piezoelectric manganese doping
Funding OrganizationNational Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation
DOI10.1021/acsami.8b14958
WOS KeywordFREE PIEZOCERAMICS ; FREE CERAMICS ; PHASE-BOUNDARY ; CRYSTALS ; STRAIN ; DOMAINS ; ORIGIN
Indexed BySCI
Language英语
Funding ProjectNational Nature Science Foundation of China[51332002] ; National Nature Science Foundation of China[51572143] ; National Nature Science Foundation of China[51522212] ; National Nature Science Foundation of China[51702252] ; Science Challenge Project[JCKY2016212A503] ; China Postdoctoral Science Foundation[2016M602812]
Funding OrganizationNational Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; Science Challenge Project ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation ; China Postdoctoral Science Foundation
WOS Research AreaScience & Technology - Other Topics ; Materials Science
WOS SubjectNanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000449239600079
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/34061
Collection中科院强磁场科学中心
Corresponding AuthorWang, Ke; Li, Jing-Feng
Affiliation1.Tsinghua Univ, State Key Lab New Ceram & Fine Proc, Sch Mat Sci & Engn, Beijing 100084, Peoples R China
2.Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Sch Mat Sci & Engn, Xian 710049, Shaanxi, Peoples R China
3.Xi An Jiao Tong Univ, Elect Mat Res Lab, Key Lab, Minist Educ, Xian 710049, Shaanxi, Peoples R China
4.Xi An Jiao Tong Univ, Int Ctr Dielect Res, Xian 710049, Peoples R China
5.Chinese Acad Sci, Inst Opt & Elect, Chengdu 610209, Sichuan, Peoples R China
6.Univ Sci & Technol China, High Magnet Field Lab, Chinese Acad Sci, Hefei Natl Lab Phys Sci Microscale, Hefei 230031, Anhui, Peoples R China
7.Univ Arkansas, Phys Dept, Fayetteville, AR 72701 USA
8.Univ Arkansas, Inst Nanosci & Engn, Fayetteville, AR 72701 USA
9.Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
10.Collaborat Innovat Ctr Quantum Matter, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Yao, Fang-Zhou,Zhang, Mao-Hua,Wang, Ke,et al. Refreshing Piezoelectrics: Distinctive Role of Manganese in Lead Free Perovskites[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(43):37298-37306.
APA Yao, Fang-Zhou.,Zhang, Mao-Hua.,Wang, Ke.,Zhou, Jia-Jun.,Chen, Feng.,...&Li, Jing-Feng.(2018).Refreshing Piezoelectrics: Distinctive Role of Manganese in Lead Free Perovskites.ACS APPLIED MATERIALS & INTERFACES,10(43),37298-37306.
MLA Yao, Fang-Zhou,et al."Refreshing Piezoelectrics: Distinctive Role of Manganese in Lead Free Perovskites".ACS APPLIED MATERIALS & INTERFACES 10.43(2018):37298-37306.
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