Institutional Repository of Chinese Acad Sci, Inst Solid State Phys, Hefei 230031, Anhui, Peoples R China
X-Shaped alpha-FeOOH with Enhanced Charge Separation for Visible-Light-Driven Photocatalytic Overall Water Splitting | |
Wang, Tianqi1; Jiang, Zhifeng1,2; Chu, Ka Him1; Wu, Dan1; Wang, Bo1; Sun, Hongli1; Yip, Ho Yin1; An, Taicheng3; Zhao, Huijun4,5; Wong, Po Keung1 | |
2018-04-25 | |
发表期刊 | CHEMSUSCHEM |
ISSN | 1864-5631 |
摘要 | Photocatalytic overall water splitting (POWS) is a promising route for converting solar energy into green and sustainable energy. Herein, we report a facile hydrothermal approach for the fabrication of x-shaped alpha-FeOOH photocatalysts containing high-index facets for POWS. The x-shaped alpha-FeOOH photocatalysts exhibited enhanced visible-light-driven POWS activities in comparison with that of FeOOH without x-structures, with a maximum H-2 and O-2 evolution rate of 9.2 and 4.7 mu mol h(-1) g(-1), respectively. The morphology and particle size of the alpha-FeOOH could be controlled by adjusting the NH4F concentration in the precursors. The photodeposition of Pt and RuO2 on the x-shaped alpha-FeOOH revealed the specially separated reduction and oxidation centers on the surface of alpha-FeOOH, with the oxidation-active sites selectively located on the edges of the alpha-FeOOH x-structures. Electrochemical experiments further affirmed the enhanced charge separation in the x-shaped alpha-FeOOH. The smaller particle size and unique x-shape of the alpha-FeOOH photocatalyst were shown to enhance the POWS performance owing to the large specific surface area, high proportion of exposed high-index facets, high electron-transfer efficiency and effective separation of the photogenerated electron-hole pairs. The current study revealed that the x-shaped alpha-FeOOH products could serve as cost-effective and stable photocatalysts for POWS. |
关键词 | charge separation high-index facets iron oxyhydroxide photocatalysis water splitting |
DOI | 10.1002/cssc.201800059 |
关键词[WOS] | GRAPHITIC CARBON NITRIDE ; HIGH-INDEX FACETS ; EFFICIENT ; HEMATITE ; OXIDE ; OXYHYDROXIDE ; DEGRADATION ; IRRADIATION ; COMPOSITE ; EVOLUTION |
收录类别 | SCI |
语种 | 英语 |
资助项目 | Hong Kong Scholar Program, China[XJ2016034] ; Postdoctoral Research Funding of Jiangsu Province[1701102B] ; Natural Science Foundation of Jiangsu[BK20170527] ; National Natural Science Foundation[21706102] ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China[2015HSC-UE004] ; ITSP Tier 3 Scheme from Innovation and Technology Commission of Hong Kong SAR Government[ITS/216/14] ; Research Grant Council[GRF14100115] ; Research Grant Council[GRF14100115] ; ITSP Tier 3 Scheme from Innovation and Technology Commission of Hong Kong SAR Government[ITS/216/14] ; CAS/SAFEA International Partnership Program for Creative Research Teams of Chinese Academy of Sciences, China[2015HSC-UE004] ; National Natural Science Foundation[21706102] ; Natural Science Foundation of Jiangsu[BK20170527] ; Postdoctoral Research Funding of Jiangsu Province[1701102B] ; Hong Kong Scholar Program, China[XJ2016034] |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
WOS类目 | Chemistry, Multidisciplinary ; GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY |
WOS记录号 | WOS:000430914600013 |
出版者 | WILEY-V C H VERLAG GMBH |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/35514 |
专题 | 中科院固体物理研究所 |
通讯作者 | Jiang, Zhifeng; Wong, Po Keung |
作者单位 | 1.Chinese Univ Hong Kong, Sch Life Sci, Shatin, Hong Kong, Peoples R China 2.Jiangsu Univ, Inst Energy Res, Sch Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China 3.Guangdong Univ Technol, Inst Environm Hlth & Pollut Control, Sch Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China 4.Griffith Univ, Griffith Scholl Environm, Ctr Clean Environm & Energy, Callaghan, NSW 4222, Australia 5.Chinese Acad Sci, Inst Solid State Phys, Lab Nanomat & Nanostruct, Hefei 230031, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Tianqi,Jiang, Zhifeng,Chu, Ka Him,et al. X-Shaped alpha-FeOOH with Enhanced Charge Separation for Visible-Light-Driven Photocatalytic Overall Water Splitting[J]. CHEMSUSCHEM,2018,11(8):1365-1373. |
APA | Wang, Tianqi.,Jiang, Zhifeng.,Chu, Ka Him.,Wu, Dan.,Wang, Bo.,...&Wong, Po Keung.(2018).X-Shaped alpha-FeOOH with Enhanced Charge Separation for Visible-Light-Driven Photocatalytic Overall Water Splitting.CHEMSUSCHEM,11(8),1365-1373. |
MLA | Wang, Tianqi,et al."X-Shaped alpha-FeOOH with Enhanced Charge Separation for Visible-Light-Driven Photocatalytic Overall Water Splitting".CHEMSUSCHEM 11.8(2018):1365-1373. |
条目包含的文件 | 下载所有文件 | |||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | ||
X-Shaped alpha-FeOOH(2828KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | 浏览 下载 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论