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Two-Way Transformation between fcc- and Nonfcc-Structured Gold Nanoclusters
Dong, Hongwei1,2; Liao, Lingwen1; Wu, Zhikun1
2017-11-02
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY LETTERS
ISSN1948-7185
Abstract

Precisely tuning the structure of nanomaterials, especially in a two-way style, is challenging but of great importance for regulating properties and for practical applications. The structural transformation from nonfcc to fcc (face center cubic) in gold nanoclusters has been recently reported; however, the reverse process, that is, the structural transformation from fcc to nonfcc, not to mention the two-way structural transformation between fcc and nonfcc, remains unknown. We developed a novel synthesis method, successfully fulfilled the two-way structure transformation, and studied the stability of gold nanoclusters with different structures. Additionally, a novel gold nanocluster was synthesized and structurally resolved by single-crystal X-ray crystallography. This work has important implications for structure and property tuning of gold nanoclusters and might open up some new potential applications for gold nanoclusters.

DOI10.1021/acs.jpclett.7b02459
WOS KeywordPHASE-TRANSFORMATION ; METAL NANOCLUSTERS ; OPTICAL-PROPERTIES ; CRYSTAL-STRUCTURE ; ATOMIC-STRUCTURE ; NANOPARTICLES ; CLUSTERS ; SIZE ; BCC ; PHOTOLUMINESCENCE
Indexed BySCI
Language英语
Funding ProjectHundred Talents Program of the Chinese Academy of Sciences ; Hefei Science Center, CAS[2015HSC-UP003] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2014FXCX002] ; National Basic Research Program of China[2013CB934302] ; Natural Science Foundation of China[21171170] ; Natural Science Foundation of China[21771186] ; Natural Science Foundation of China[21603234] ; Natural Science Foundation of China[21528303] ; Natural Science Foundation of China[21222301] ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of China[21222301] ; Natural Science Foundation of China[21528303] ; Natural Science Foundation of China[21603234] ; Natural Science Foundation of China[21771186] ; Natural Science Foundation of China[21171170] ; National Basic Research Program of China[2013CB934302] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2014FXCX002] ; Hefei Science Center, CAS[2015HSC-UP003] ; Hundred Talents Program of the Chinese Academy of Sciences
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Atomic, Molecular & Chemical
WOS IDWOS:000414623000017
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/35683
Collection中科院固体物理研究所
Corresponding AuthorWu, Zhikun
Affiliation1.Chinese Acad Sci, Inst Solid State Phys, Anhui Key Lab Nanomat & Nanotechnol, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China
2.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China
Recommended Citation
GB/T 7714
Dong, Hongwei,Liao, Lingwen,Wu, Zhikun. Two-Way Transformation between fcc- and Nonfcc-Structured Gold Nanoclusters[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2017,8(21):5338-5343.
APA Dong, Hongwei,Liao, Lingwen,&Wu, Zhikun.(2017).Two-Way Transformation between fcc- and Nonfcc-Structured Gold Nanoclusters.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,8(21),5338-5343.
MLA Dong, Hongwei,et al."Two-Way Transformation between fcc- and Nonfcc-Structured Gold Nanoclusters".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 8.21(2017):5338-5343.
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