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Charge and Bonding in CuGeO3 Nanorods
O'Neal, Kenneth R.1; al-Wahish, Aural1; Li, Zhao-Qian2; Dhalenne, Guy3; Revcolevschi, Alexandre3; Chen, Xue-Tai4; Musfeldt, Janice L.1,5
2018-06-01
Source PublicationNANO LETTERS
ISSN1530-6984
Volume18Issue:6Pages:3428-3434
Corresponding AuthorMusfeldt, Janice L.(musfeldt@utk.edu)
AbstractWe combine infrared and Raman spectroscopies to investigate finite length scale effects in CuGeO3 nanorods. The infrared-active phonons display remarkably strong size dependence whereas the Raman-active features are, by comparison, nearly rigid. A splitting analysis of the Davydov pairs reveals complex changes in chemical bonding with rod length and temperature. Near the spin-Peierls transition, stronger intralayer bonding in the smallest rods indicates a more rigid lattice which helps to suppress the spin-Peierls transition. Taken together, these findings advance the understanding of size effects and collective phase transitions in low-dimensional oxides.
KeywordSpin-Peierls transition magnetoelastic coupling size effects phonon confinement nanorods vibrational spectroscopy
Funding OrganizationMaterials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy
DOI10.1021/acs.nanolett.8b00407
WOS KeywordSPIN-PEIERLS TRANSITION ; FERROELECTRIC PHASE-TRANSITION ; COMPOUND CUGEO3 ; HEMATITE NANOPARTICLES ; MAGNETIC-PROPERTIES ; CRYSTAL-STRUCTURE ; LIGHT-SCATTERING ; DOPED CUGEO3 ; PRESSURE ; DIAGRAM
Indexed BySCI
Language英语
Funding ProjectMaterials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy[DE-FG02-01ER45885] ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy[DE-FG02-01ER45885]
Funding OrganizationMaterials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy ; Materials Science Division, Office of Basic Energy Sciences, U.S. Department of Energy
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS SubjectChemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS IDWOS:000435524300016
PublisherAMER CHEMICAL SOC
Citation statistics
Document Type期刊论文
Identifierhttp://ir.hfcas.ac.cn:8080/handle/334002/37188
Collection应用技术研究所
Corresponding AuthorMusfeldt, Janice L.
Affiliation1.Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
2.Chinese Acad Sci, Inst Appl Technol, Hefei Inst Phys Sci, Hefei 230031, Anhui, Peoples R China
3.Univ Paris Saclay, ICMMO SP2M, UMR CNRS 8182, F-91405 Orsay, France
4.Nanjing Univ, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Nanjing 210023, Jiangsu, Peoples R China
5.Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA
Recommended Citation
GB/T 7714
O'Neal, Kenneth R.,al-Wahish, Aural,Li, Zhao-Qian,et al. Charge and Bonding in CuGeO3 Nanorods[J]. NANO LETTERS,2018,18(6):3428-3434.
APA O'Neal, Kenneth R..,al-Wahish, Aural.,Li, Zhao-Qian.,Dhalenne, Guy.,Revcolevschi, Alexandre.,...&Musfeldt, Janice L..(2018).Charge and Bonding in CuGeO3 Nanorods.NANO LETTERS,18(6),3428-3434.
MLA O'Neal, Kenneth R.,et al."Charge and Bonding in CuGeO3 Nanorods".NANO LETTERS 18.6(2018):3428-3434.
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