Ultrathin Transition Metal Dichalcogenide/3d Metal Hydroxide Hybridized Nanosheets to Enhance Hydrogen Evolution Activity

doi:10.1002/adma.201801171

HFCAS OpenIR > 中科院固体物理研究所

	Ultrathin Transition Metal Dichalcogenide/3d Metal Hydroxide Hybridized Nanosheets to Enhance Hydrogen Evolution Activity
	Zhu, Zhengju 1; Yin, Huajie 1; He, Chun-Ting 1,2; Al-Mamun, Mohammad 1; Liu, Porun 1; Jiang, Lixue 1; Zhao, Yong 3; Wang, Yun1 ; Yang, Hua-Gui 1; Tang, Zhiyong 1; Wang, Dan 1; Chen, Xiao-Ming 2; Zhao, Huijun 1,4
	2018-07-12
发表期刊	ADVANCED MATERIALS
ISSN	0935-9648
通讯作者	Yin, Huajie(h.yin@griffith.edu.au) ; Zhao, Huijun(h.zhao@griffith.edu.au)
摘要	The vast majority of the reported hydrogen evolution reaction (HER) electrocatalysts perform poorly under alkaline conditions due to the sluggish water dissociation kinetics. Herein, a hybridization catalyst construction concept is presented to dramatically enhance the alkaline HER activities of catalysts based on 2D transition metal dichalcogenides (TMDs) (MoS2 and WS2). A series of ultrathin 2D-hybrids are synthesized via facile controllable growth of 3d metal (Ni, Co, Fe, Mn) hydroxides on the monolayer 2D-TMD nanosheets. The resultant Ni(OH)(2) and Co(OH)(2) hybridized ultrathin MoS2 and WS2 nanosheet catalysts exhibit significantly enhanced alkaline HER activity and stability compared to their bare counterparts. The 2D-MoS2/Co(OH)(2) hybrid achieves an extremely low overpotential of approximate to 128 mV at 10 mA cm(-2) in 1 M KOH. The combined theoretical and experimental studies confirm that the formation of the heterostructured boundaries by suitable hybridization of the TMD and 3d metal hydroxides is responsible for the improved alkaline HER activities because of the enhanced water dissociation step and lowers the corresponding kinetic energy barrier by the hybridized 3d metal hydroxides.
关键词	2D materials electrocatalysis hydrogen evolution reaction metal hydroxides transition metal dichalcogenides
DOI	10.1002/adma.201801171
关键词[WOS]	MOS2 NANOSHEETS ; EDGE SITES ; ENERGY-CONVERSION ; CATALYSTS ; WATER ; DESIGN ; NANOCOMPOSITES ; COMPOSITES ; ELECTRODES ; PLATINUM
收录类别	SCI
语种	英语
资助项目	Australian Research Council (ARC) Discovery Project[DP170104834] ; National Natural Science Foundation of China[51372248] ; National Natural Science Foundation of China[51432009] ; Griffith University Postdoctoral Fellowship ; National Postdoctoral Program for Innovative Talents[BX201600195] ; Australian Research Council (ARC) Discovery Project[DP170104834] ; National Natural Science Foundation of China[51372248] ; National Natural Science Foundation of China[51432009] ; Griffith University Postdoctoral Fellowship ; National Postdoctoral Program for Innovative Talents[BX201600195]
项目资助者	Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; Australian Research Council (ARC) Discovery Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; Griffith University Postdoctoral Fellowship ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents ; National Postdoctoral Program for Innovative Talents
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目	Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter
WOS记录号	WOS:000439994500025
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：183[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/37652
专题	中科院固体物理研究所
通讯作者	Yin, Huajie; Zhao, Huijun
作者单位	1.Griffith Univ, Ctr Clean Environm & Energy, Southport, Qld 4222, Australia 2.Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China 3.Univ Wollongong, Intelligent Polymer Res Inst, ARC Ctr Excellence Electromat Sci, AIIM Innovat Campus, North Wollongong, NSW 2522, Australia 4.Chinese Acad Sci, Inst Solid State Phys, CAS Ctr Excellence Nanosci, Ctr Environm & Energy Nanomat, Hefei 230031, Anhui, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Zhengju,Yin, Huajie,He, Chun-Ting,et al. Ultrathin Transition Metal Dichalcogenide/3d Metal Hydroxide Hybridized Nanosheets to Enhance Hydrogen Evolution Activity[J]. ADVANCED MATERIALS,2018,30(28):7.
APA	Zhu, Zhengju.,Yin, Huajie.,He, Chun-Ting.,Al-Mamun, Mohammad.,Liu, Porun.,...&Zhao, Huijun.(2018).Ultrathin Transition Metal Dichalcogenide/3d Metal Hydroxide Hybridized Nanosheets to Enhance Hydrogen Evolution Activity.ADVANCED MATERIALS,30(28),7.
MLA	Zhu, Zhengju,et al."Ultrathin Transition Metal Dichalcogenide/3d Metal Hydroxide Hybridized Nanosheets to Enhance Hydrogen Evolution Activity".ADVANCED MATERIALS 30.28(2018):7.