A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds

doi:10.1002/anie.201805594

HFCAS OpenIR > 中科院固体物理研究所

	A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds
	Liu, Xu 1,2,3; Chen, Jishi 1; Yuan, Jinyun 4; Li, Yizhi 5; Li, Jin 6; Zhou, Shiming 4; Yao, Chuanhao 1; Liao, Lingwen1 ; Zhuang, Shengli 1,2,3; Zhao, Yan 1,2,3; Deng, Haiteng 6; Yang, Jinlong 4; Wu, Zhikun1,3
	2018-08-27
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN	1433-7851
通讯作者	Yang, Jinlong(jlyang@ustc.edu.cn) ; Wu, Zhikun(zkwu@issp.ac.cn)
摘要	The emergence of thiolated metal nanoclusters provides opportunities to identify significant and unprecedented phenomena because they are at quantum sizes and can be characterized with X-ray crystallography. Recently silver nanoclusters have received extensive interest owing to their merits, such as low-cost and rich properties. Herein, a thiolated silver nanocluster [Ag46S7(SPhMe2)(24)]NO3 (Ag-46 for short) with a face-centered cubic (fcc) structure was successfully synthesized and structurally resolved by X-ray analysis. Most importantly, interstitial sulfur was found in the lattice void of Ag-46 without lattice distortion or expansion, indicating that the classic theory of interstitial metal solid solutions might be not applicable at quantum size. Furthermore, unprecedented chemical bonds and unique structural features (such as asymmetrically coordinated mu(4)-S) were found in Ag-46 and might be related to the interstitial sulfur, which is supported by natural population analyses.
关键词	interstitial sulfur nanoclusters photoluminescence silver structure
DOI	10.1002/anie.201805594
关键词[WOS]	PROTECTED GOLD CLUSTERS ; THEORETICAL-ANALYSIS ; CRYSTAL-STRUCTURE ; SOLID-SOLUTIONS ; NANOPARTICLES ; ATOMS ; RESOLUTION ; COMPLEXES ; AU-25
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[21601193] ; National Natural Science Foundation of China[21603234] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21528303] ; National Key Research & Development Program of China[2016YFA0200604] ; Key Program of 13th five-year plan ; CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002] ; CAS/SAFEA International Partnership Program for Creative Research Teams ; National Natural Science Foundation of China[21171170] ; National Natural Science Foundation of China[21771186] ; National Natural Science Foundation of China[21688102] ; National Natural Science Foundation of China[21601193] ; National Natural Science Foundation of China[21603234] ; National Natural Science Foundation of China[21222301] ; National Natural Science Foundation of China[21528303] ; National Key Research & Development Program of China[2016YFA0200604] ; Key Program of 13th five-year plan ; CASHIPS[KP-2017-16] ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology[2017FXCX002] ; CAS/SAFEA International Partnership Program for Creative Research Teams
项目资助者	National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; 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CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; National Key Research & Development Program of China ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; Key Program of 13th five-year plan ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; CASHIPS ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000442340000026
出版者	WILEY-V C H VERLAG GMBH
引用统计	被引频次：45[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/38609
专题	中科院固体物理研究所
通讯作者	Yang, Jinlong; Wu, Zhikun
作者单位	1.Chinese Acad Sci, Inst Solid State Phys, CAS Ctr Excellence Nanosci, Key Lab Mat Phys,Anhui Key Lab Nanomat & Nanotech, Hefei 230031, Anhui, Peoples R China 2.Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Anhui, Peoples R China 3.Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China 4.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 5.Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China 6.Tsinghua Univ, Sch Life Sci, Tsinghua Univ Peking Univ Joint Ctr Life Sci, Beijing 100084, Peoples R China
推荐引用方式 GB/T 7714	Liu, Xu,Chen, Jishi,Yuan, Jinyun,et al. A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(35):11273-11277.
APA	Liu, Xu.,Chen, Jishi.,Yuan, Jinyun.,Li, Yizhi.,Li, Jin.,...&Wu, Zhikun.(2018).A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(35),11273-11277.
MLA	Liu, Xu,et al."A Silver Nanocluster Containing Interstitial Sulfur and Unprecedented Chemical Bonds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.35(2018):11273-11277.