Institutional Repository of Chinese Acad Sci, Hefei Inst Phys Sci, Inst Appl Technol,Hefei 230031, Anhui, Peoples R China
A Simple Carbazole-Triphenylamine Hole Transport Material for Perovskite Solar Cells | |
Liu, Xuepeng1; Shi, Xiaoqiang1; Liu, Cheng1; Ren, Yingke1; Wu, Yunzhao1; Yang, Weng1; Alsaedi, Ahmed3; Hayat, Tasawar3,4; Kong, Fantai2; Liu, Xiaolong1; Ding, Yong1; Yao, Jianxi1; Dai, Songyuan1 | |
2018-11-22 | |
发表期刊 | JOURNAL OF PHYSICAL CHEMISTRY C |
ISSN | 1932-7447 |
通讯作者 | Kong, Fantai(kongfantai@163.com) ; Dai, Songyuan(sydai@ncepu.edu.cn) |
摘要 | In this work, a simple carbazole-based hole transport material with triphenylamine moieties, termed LD22, has been used in perovskite solar cells (PSCs). It is noted that LD22 exhibits a proper HOMO level of -5.27 eV, high hole mobility of 1.65 X 10(-5) cm(2) V-1 s(-1), and relatively high glass-transition temperature of 132 degrees C. When LD22 was used in PSCs, pristine LD22-based PSCs showed a power conversion efficiency (PCE) of 13.04%. When LD22 is doped, the PCE improves to a promising 17.18%. More importantly, the concentration of LD22 has little influence on the PSC performance regardless of the existence of dopants, which shows good repeatability. As a reference, the device with doped 2,2',7,7'-tetrakis(N,N-bis(4-methoxyphenyl)amino)-9,9'-spiro-bifluorene (spiro-OMeTAD) shows a PCE of 17.73%. On the other hand, the laboratory synthesis cost of LD22 is much lower than that of spiro-OMeTAD. Therefore, the results indicate that the simple carbazole-triphenylamine compounds own the potential to be doped-free HTM and LD22 could be a promising HTM candidate for high-performance PSCs due to its simple structure. |
DOI | 10.1021/acs.jpcc.8b08168 |
关键词[WOS] | HIGHLY EFFICIENT ; DOPANT-FREE ; PI-LINKER ; LOW-COST ; DERIVATIVES ; (2-ETHYLHEXYL)-9H-CARBAZOLE |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Key Research and Development Program of China[2016YFA0202400] ; National Key Basic Research Program of China (973 Program)[2015CB932201] ; National Natural Science Foundation of China[51702096] ; National Natural Science Foundation of China[61705066] ; National Key Research and Development Program of China[2016YFA0202400] ; National Key Basic Research Program of China (973 Program)[2015CB932201] ; National Natural Science Foundation of China[51702096] ; National Natural Science Foundation of China[61705066] |
项目资助者 | National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Basic Research Program of China (973 Program) ; National Key Basic Research Program of China (973 Program) ; National Key Basic Research Program of China (973 Program) ; National Key Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; National Key Basic Research Program of China (973 Program) ; National Key Basic Research Program of China (973 Program) ; National Key Basic Research Program of China (973 Program) ; National Key Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
WOS类目 | Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
WOS记录号 | WOS:000451495600004 |
出版者 | AMER CHEMICAL SOC |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/40512 |
专题 | 应用技术研究所 |
通讯作者 | Kong, Fantai; Dai, Songyuan |
作者单位 | 1.North China Elect Power Univ, Beijing Key Lab Novel Thin Film Solar Cells, Beijing 102206, Peoples R China 2.Chinese Acad Sci, Hefei Inst Phys Sci, Inst Appl Technol, Key Lab Photovolta & Energy Conservat Mat, Hefei 230088, Anhui, Peoples R China 3.King Abdulaziz Univ, Dept Math, NAAM Res Grp, Fac Sci, Jeddah 21589, Saudi Arabia 4.Quaid I Azam Univ, Dept Math, Islamabad 44000, Pakistan |
推荐引用方式 GB/T 7714 | Liu, Xuepeng,Shi, Xiaoqiang,Liu, Cheng,et al. A Simple Carbazole-Triphenylamine Hole Transport Material for Perovskite Solar Cells[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2018,122(46):26337-26343. |
APA | Liu, Xuepeng.,Shi, Xiaoqiang.,Liu, Cheng.,Ren, Yingke.,Wu, Yunzhao.,...&Dai, Songyuan.(2018).A Simple Carbazole-Triphenylamine Hole Transport Material for Perovskite Solar Cells.JOURNAL OF PHYSICAL CHEMISTRY C,122(46),26337-26343. |
MLA | Liu, Xuepeng,et al."A Simple Carbazole-Triphenylamine Hole Transport Material for Perovskite Solar Cells".JOURNAL OF PHYSICAL CHEMISTRY C 122.46(2018):26337-26343. |
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