含铅污泥中Pb的激光诱导击穿光谱定量反演研究

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	含铅污泥中Pb的激光诱导击穿光谱定量反演研究
其他题名	Quantitative retrieval research of Pb in lead slime by laser induced breakdown spectroscopy
	余洋 1; 赵南京1 ; 王寅 1; 方丽1 ; 孟德硕1 ; 胡丽 1; 马明俊1 ; 刘建国1
	2015
发表期刊	激光技术
ISSN	1001-3806
摘要	为了实现含铅污泥中Pb的快速定量反演分析,选取PbⅠ：405.78nm为分析线,从谱线强度、信背比以及信号的相对标准偏差三方面研究了激光能量对含铅污泥中铅的激光诱导击穿光谱特性的影响。在23.1mJ-135.4mJ范围内,谱线强度随激光能量线性增加,信背比先增加后降低最终趋于稳定,信号的相对标准偏差随着激光能量的增加先减小后趋于稳定。配制了不同质量分数含铅污泥的样品,获得了铅的定标曲线。结果表明,在质量分数为0.001118-0.020115范围内,谱线强度与Pb含量之间有较好的线性关系,相关系数达到0.991;在此方法下,得到含铅污泥的Pb含量测量值与实际值之间的相对误差为8.72%。此方法能够实现含铅污泥中Pb的快速定量反演检测。
其他摘要	In order to achieve fast quantitative retrieval analysis of Pb in lead slime,PbⅠ：405. 78 nm was selected as the analytical line. The influences of laser energy on the laser induced breakdown spectroscopy characteristics of Pb in lead slime were discussed from three areas of spectral intensity,the ratio of signal and background and the relative standard deviation of signal. Within the range of 23. 1mJ - 135. 4mJ,line intensity increases linearly with the increase of laser energy,the ratio of signal and background increases at first and then decreases,and eventually stabilizes. The relative standard deviation of the signal decreases at first and then stabilizes with the increase of laser energy. The samples of lead slime with different mass fractions were prepared and the calibration curve of Pb was obtained. The results show that within the range of mass fraction of 0. 001118 - 0. 20115,spectrum intensity has the good linear relationship with Pb content. The correlation coefficient reaches 0. 991. With this method,the relative error between measurement value and real value of Pb content of lead slime is 8. 72%. This method can provide fast and quantitative retrieval measurement of Pb in lead slime.
关键词	光谱学激光诱导击穿光谱含铅污泥激光能量定量反演分析
收录类别	CSCD
语种	中文
CSCD记录号	CSCD:5472650
引用统计
文献类型	期刊论文
条目标识符	http://ir.hfcas.ac.cn:8080/handle/334002/49327
专题	中国科学院合肥物质科学研究院
作者单位	1.中国科学院安徽光学精密机械研究所 2.中国科学院安徽光学精密机械研究所 3.中国科学院安徽光学精密机械研究所 4.中国科学院安徽光学精密机械研究所 5.中国科学院安徽光学精密机械研究所 6.中国科学院安徽光学精密机械研究所 7.中国科学院安徽光学精密机械研究所 8.中国科学院安徽光学精密机械研究所
推荐引用方式 GB/T 7714	余洋,赵南京,王寅,等. 含铅污泥中Pb的激光诱导击穿光谱定量反演研究[J]. 激光技术,2015,039.
APA	余洋.,赵南京.,王寅.,方丽.,孟德硕.,...&刘建国.(2015).含铅污泥中Pb的激光诱导击穿光谱定量反演研究.激光技术,039.
MLA	余洋,et al."含铅污泥中Pb的激光诱导击穿光谱定量反演研究".激光技术 039(2015).