Institutional Repository of Chinese Academy of Sciences, Institute of Plasma Physics, Hefei 230031, Anhui, Peoples R China
基于薄膜电极溶胶修饰的染料敏化太阳电池光电特性研究 | |
徐炜炜; 胡林华; 罗向东; 刘培生; 戴松元 | |
2012 | |
发表期刊 | 物理学报 |
其他摘要 | Nanoporous film electrode is a crucial composition of dye-sensitized solar cells, which influences the photoelectric conversion performance. To improve the property of the photoelectrode, different modification methods by using different concentrations of TiO 2 sol are investigated. The crystallite size and phase of the nanoporous TiO 2 particles and the TiO 2 sol after sintering are studied with X-ray diffraction. The microstructure morphologies of the conductive glass and the films are determined by the high resolution transmission electron microscopy and the field emission scanning electron microscopy. The influences on electron lifetime τ n and the electron transit time τ d are analyzed by intensity-modulated photocurrent spectroscopy and photovoltage spectroscopy (IMPS/IMVS) from the mechanisms of electron transport and back reaction kinetics. It is found that the back reactions are well suppressed under dark conditions after sol modifications. τ n is effectively extended and τ d is also shorten correspondingly by any kind of sol treatment. The short-current density and the photoelectric conversion efficiency are increased by 10.9% and 11.9% separately, when 0.10 mol•L 1 sol modification is applied both to the conductive glass and to the nanoporous TiO 2 film at the same time. |
关键词 | Dye-sensitized Solar Cell Sol Electron Lifetime Electron Transit Time |
文献类型 | 期刊论文 |
条目标识符 | http://ir.hfcas.ac.cn:8080/handle/334002/5426 |
专题 | 中科院等离子体物理研究所 |
推荐引用方式 GB/T 7714 | 徐炜炜,胡林华,罗向东,等. 基于薄膜电极溶胶修饰的染料敏化太阳电池光电特性研究[J]. 物理学报,2012(4):1+8. |
APA | 徐炜炜,胡林华,罗向东,刘培生,&戴松元.(2012).基于薄膜电极溶胶修饰的染料敏化太阳电池光电特性研究.物理学报(4),1+8. |
MLA | 徐炜炜,et al."基于薄膜电极溶胶修饰的染料敏化太阳电池光电特性研究".物理学报 .4(2012):1+8. |
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